413614-56-9

Upstream product

• 42854-62-6 L-alanine benzyl ester p-toluenesulfonate 
• 106-95-6 allyl bromide 
• 17831-01-5 H-Ala-OBzl 

Downstream Products

• 413614-57-0 benzyl N-(1-prop-2-enyl)-N-(1,4-dioxobutyl)-L-alaninate 
• 1084953-63-8 Z-Ala-N-allyl-Ala-OBn 
• 1084953-75-2 Z-Thr(OTBS)-N-allyl-Ala-OBn 
• 1084953-76-3 Z-Pro-N-allyl-Ala-OBn 
• 1259391-77-9 C₃₂H₄₃F₆N₃O₈ 
• 1259392-00-1 C₃₂H₄₃F₆N₃O₈ 
• 1259391-62-2 C₂₅H₃₃F₆N₃O₄ 
• 1307893-46-4 C₁₈H₂₅NO₄ 
• 413614-58-1 benzyl N-(1-prop-2-enyl)-N-(1,4-dioxo-2-chlorobutyl)-L-alaninate 

Relevant academic research and scientific papers

Asymmetric carbonyl migration of α-amino acid derivatives via memory of chirality

N-tert-Butoxycarbonylcarbamates of α-amino acid derivatives underwent asymmetric carbonyl migration by treatment with KHMDS in DMF to give α-amino acid derivatives with an additional ester group at the newly formed tetrasubstituted carbon center in up to 99% ee. Georg Thieme Verlag Stuttgart.

A method for cleaving an allyl protecting group at the amide nitrogen of peptides by one-pot olefin isomerization-oxidation

(Chemical Equation Presented) A facile method for N-deallylation at the amide nitrogen of peptides is described. One-pot deallylation of a substrate through ruthenium hydride-catalyzed terminal olefin isomerization and subsequent ozonolysis gave the corresponding deallylated product under mild conditions.

Synthesis of enantiopure pyrrolo[3,4-c]pyrazole derivatives via intramolecular cycloaddition of homochiral nitrilimines

Intramolecular cycloaddition of homochiral nitrilimines 8 was exploited to obtain enantiopure pyrrolo[3,4-c]pyrazole derivatives 9 and 10 with high overall yields.