414860-13-2Relevant academic research and scientific papers
Hetero-binuclear complexes containing a Ru0 → Mn+ bond bridged by P,N-phosphine ligands: Convenient synthesis of tridentate organometallic trans-Ru(CO)3(L)2 (L = phosphine bearing an N-donor substituent) ligands
Song, Hai-Bin,Zhang, Zheng-Zhi,Mak, Thomas C.W.
, p. 113 - 119 (2007/10/03)
A convenient new synthesis of trans-Ru(CO)3(μ-L)2 [L = 2-(diphenylphosphino)pyridine, N-(diphenylphosphinomethyl)morpholine)] was developed. The reactions of these two tridentate organometallic ligands with selected group 11 and 12 metal salts resulted in the formation of hetero-binuclear Ru0 → Mn+ [M = Ag(I), n = 1; Hg(II), Cd(II), n = 2] complexes with Ru-Ag = 2.7132(7) A, Ru-Hg = 2.7075(4) A and Ru-Cd = 2.7750(9) A, as determined by X-ray crystallography.
