41498-71-9 Usage
Uses
Used in Chemical Synthesis:
Exo-2-Norbornyl formate is used as a key intermediate in the synthesis of various complex organic molecules. Its unique structure allows it to undergo a range of chemical reactions, making it a valuable building block for the creation of new compounds with potential applications in various industries.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, exo-2-norbornyl formate is used as a starting material for the synthesis of novel drug candidates. Its ability to participate in ruthenium-catalyzed transformations enables the development of new molecules with potential therapeutic properties.
Used in Material Science:
Exo-2-Norbornyl formate is also utilized in the field of material science, where it is used to create new polymers and materials with specific properties. Its reactivity and structural characteristics make it a useful component in the development of advanced materials with applications in various sectors, such as electronics, automotive, and aerospace industries.
Used in Research and Development:
Exo-2-Norbornyl formate is an important compound in academic and industrial research and development. Its unique reactivity and participation in ruthenium-catalyzed transformations make it a valuable tool for studying new reaction mechanisms and developing innovative synthetic methods. This contributes to the advancement of knowledge in the field of organic chemistry and the discovery of new compounds with potential applications in various industries.
Purification Methods
Shake with NaHCO3 and distil it in vacuo (exo-borneol has m 124-126o). Alternatively mix the ester with formic acetic anhydride overnight and fractionate. [Beilstein 6 III 219.]
Check Digit Verification of cas no
The CAS Registry Mumber 41498-71-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 4,1,4,9 and 8 respectively; the second part has 2 digits, 7 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 41498-71:
(7*4)+(6*1)+(5*4)+(4*9)+(3*8)+(2*7)+(1*1)=129
129 % 10 = 9
So 41498-71-9 is a valid CAS Registry Number.
InChI:InChI=1/C8H12O2/c9-5-10-8-4-6-1-2-7(8)3-6/h5-8H,1-4H2/t6-,7+,8+/m0/s1
41498-71-9Relevant academic research and scientific papers
Dual behavior of alcohols in iodine-catalyzed esterification under solvent-free reaction conditions
Jereb, Marjan,Vra?i?, Dejan,Zupan, Marko
body text, p. 2347 - 2352 (2009/09/06)
The dual behavior phenomenon of alcohols in iodine-catalyzed esterification under solvent-free reaction conditions (SFRCs) is described; the governing factor is the stability of the carbonium ion generated from the alcohol; high concentration reaction conditions (HCRCs) or dilute solutions are much less suitable. In the case of benzylic alcohols, loss of optical activity was noted, whereas alkyl alcohols furnished a product with retention of stereochemistry.
Synthesis of esters by addition of carboxylic acids to cage cycloolefins
Mamedov
, p. 165 - 168 (2007/10/03)
The thermal addition of monocarboxylic acids to cage bi-, tri-, tetra-, and pentacyclic hydrocarbons was carried out, and a highly efficient wasteless method of preparing esters of the corresponding alcohols was developed. The reaction has no need for Lewis acids as special catalysts since the initial acids themselves function as both catalyst and reagent. Orientation of the formyloxy and acyloxy groups in cycloolefin hydrocarbons was found, and the degree of regio- and stereoselectivity of the reaction was determined. A number of new esters of polycyclic alcohols were prepared. Some of them are of interest for perfumes.
PREPARATION OF BICYCLIC ESTERS OF MONOCARBOXYLIC ACIDS
Mamedov, M. K.,Suleimanova, E. T.
, p. 944 - 947 (2007/10/02)
A method has been developed for the preparation of bicyclic esters by the cycloalkylation of C1-C3 monocarboxylic acids by norbornene hydrocarbons in the presence of p-toluenesulfonic acid as catalyst.The reaction proceeds stereoselectively with the preferential formation of an exo-isomer.
