415707-41-4

Upstream product

• 415707-43-6 ((C₄H₉)2PCH₂)2C₆H₃PtClC⁽²⁾H₂Cl⁽¹⁺⁾*B((CF₃)2C₆H₃)4^(1-)=((C₄H₉)2PCH₂)2C₆H₃PtClC⁽²⁾H₂ClB((CF₃)2C₆H₃)4 
• 1333-74-0 hydrogen 
• 60399-52-2 (2,6-bis[(di-t-butylphosphino)methyl]phenyl)hydridoplatinum 

Downstream Products

• 415707-43-6 ((C₄H₉)2PCH₂)2C₆H₃PtClC⁽²⁾H₂Cl⁽¹⁺⁾*B((CF₃)2C₆H₃)4^(1-)=((C₄H₉)2PCH₂)2C₆H₃PtClC⁽²⁾H₂ClB((CF₃)2C₆H₃)4 

Relevant academic research and scientific papers

Protonation of (PCP)PtH to give a dihydrogen complex

The protonation of (PCP)PtH (PCP=η3-2,6-(tBu2PCH2) 2C6H3) to give a (PCP)PtII dihydrogen complex was reported. The reaction was accomplished in CD2Cl2 with [H(OEt2)2]+BAr′4- [Ar′ = 3,5-bis(trifluoromethyl)phenyl]. The analysis showed that the H2 ligand was expelled when the solution was warmed to room temperature, but the dihydrogen complex was reformed when H2 was added.