41578-06-7Relevant academic research and scientific papers
A facile sulfenylchlorination of alkenes with Me2SO/(COCl)2
Lan, Liyuan,Gao, Yang,Ding, Rui,Zhang, Ting,Liu, Yongguo,Sun, Baoguo,Tian, Hongyu
supporting information, p. 539 - 549 (2019/02/01)
The sulfenylchlorination of a series of alkenes is investigated by using the combined reagent of dimethyl sulfoxide and oxalyl chloride. The corresponding β-chloro sulfides were obtained in mediate to good yields. Most of the terminal alkenes give the Mar
Metal-Free Chlorothiolation of Alkenes Using HCl and Sulfoxides
Ebule, Rene,Hammond, Gerald B.,Xu, Bo
supporting information, p. 4705 - 4708 (2018/09/06)
We report a novel method for the chlorothiolation of alkenes using HCl and sulfoxides to achieve the 1,2-difunctionalization of unactivated alkenes. The combination of our new HCl reagent (HCl/DMPU) with sulfoxides forms a unique chlorothiolation system.
A Facile Method for the Sulfenyllactonization of Alkenoic Acids Using Dimethyl Sulfoxide Activated by Oxalyl Chloride
Zhang, Ting,Dai, Yifeng,Cheng, Siwei,Liu, Yongguo,Yang, Shaoxiang,Sun, Baoguo,Tian, Hongyu
, p. 1380 - 1386 (2017/03/11)
A simple approach has been developed for the sulfenyllactonization of alkenoic acids using dimethyl sulfoxide activated with oxalyl chloride, in which methanesulfenyl chloride is proposed as the intermediate.
Conformational analysis of 1-Y, 2-Z-cyclohexanes ( Y = OH, OMe, F, Cl, Br and I; Z= SMe, SOMe and SO2Me): Study of the Z/Y gauche interactions
Carreno,Carretero,Garcia Ruano,Rodriguez
, p. 5649 - 5664 (2007/10/02)
The conformational study of the title compounds is reported. The configurational assignment of the epimeric sulfoxides was based on the relationship between the stereochemistry of the sulfinyl group and the chemical shifts of the neighboring nuclei. The v
A FACILE METHOD FOR THE SYNTHESIS OF β-CHLOROALKYL SULFIDES USING DIMETHYL SULFOXIDE ACTIVATED BY PHENYL DICHLOROPHOSPHATE OR PHOSPHORUS OXYCHLORIDE
Liu, Hsing-Jang,Nyangulu, James M.
, p. 5467 - 5470 (2007/10/02)
A simple procedure has been developed for the transformation of alkenes to β-chloroalkyl sulfides using dimethyl sulfoxide activated with phenyl dichlorophosphate or phosphorus oxychloride.
BEHAVIOR OF CYCLOALKENES IN SULFENYLCHLORINATION-DEHYDROCHLORINATION REACTIONS
Gritsenko, E. I.,Butenko, G. G.,Plemenkov, V. V.
, p. 673 - 678 (2007/10/02)
By the addition of alkanesulfenyl chlorides to cyclohexene, cyclopentene, indene, and 7-oxabenzonorbornadiene the corresponding β-chlorocycloalkyl alkyl sulfides were obtained.They were subsequently investigated in elimination reactions with alkali-metal
