41589-63-3

Usage

Synthesis Reference(s)

Tetrahedron Letters, 29, p. 5703, 1988 DOI: 10.1016/S0040-4039(00)82167-X

Upstream product

• 119814-75-4 2-[2-Hydroxy-prop-(Z)-ylidene]-hexanoic acid 
• 208048-93-5 3-Butyl-3-dimethylamino-5-methyl-dihydro-furan-2-one 
• 917-54-4 methyllithium 
• 693-02-7 hex-1-yne 
• 870-63-3 prenyl bromide 
• 111572-50-0 3-<(E)-butylidene>-5-methyldihydrofuran-2(3H)-one 
• 866538-10-5 (RS)-(Z)-4-(n-butyltellanyl)oct-3-en-2-ol 
• 124-38-9 carbon dioxide 
• 866538-06-9 (Z)-4-(n-butyltellanyl)oct-3-en-2-one 
• 868588-47-0 (E)-ethyl-2-(prop-2-enyl)hex-2-enoate 
• 3190-50-9 2,5-dimethyl-5-methylene-1,3-dioxane 
• 15975-93-6 pentacarbonyl((methyl)((tetramethylammonio)oxy)carbene)chromium⁽⁰⁾ 
• 177955-97-4 2-Allyl-hexanoic acid methyl ester 
• 119814-67-4 2-(1,2-Dihydroxy-propyl)-hexanal 

Relevant academic research and scientific papers

A convenient method for lactonization of α-allyl esters using iodine in dimethylsulphoxide

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Convenient synthesis of volatile Streptomyces lactones

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The cycloaddition of nitrones (4) to propene, followed by sequential treatment with methyl trifluoromethanesulfonate, H2-Pd/C, and m-chloroperbenzoic acid, is shown to provide a general method for the preparation of a variety of volatile streptomyces lactones.

THE SYNTHESIS OF VOLATILE STREPTOMYCES LACTONES

A synthetic pathway to the volatile streptomyces lactones has been developed using as a key step sequential addition / alkylation to anions generated from 2,2-dimethyl-5-methylene-1,3-dioxane.