415917-69-0

Upstream product

• 103-26-4 Methyl cinnamate 
• 84673-88-1 (E)-3-bromo-1-(trimethylsilyl)propene 

Downstream Products

• 415917-82-7 (1R,2R,3S)-2-Formyl-3-phenyl-cyclopropanecarboxylic acid methyl ester 
• 415917-83-8 (1R,2S,3R)-2-Phenyl-3-(3-trimethylsilanyl-oxiranyl)-cyclopropanecarboxylic acid methyl ester 

Relevant academic research and scientific papers

Controllable Diastereoselective Cyclopropanation. Enantioselective Synthesis of Vinylcyclopropanes via Chiral Telluronium Ylides

Novel chiral telluronium salts 1 are designed for asymmetric synthesis of 1,3-disubstituted 2-vinylcyclopropanes. The allylides, generated in situ from the corresponding telluronium salt in the presence of different base, reacted with α,β-unsaturated este

Enantioselective synthesis of vinylcyclopropanes and vinylepoxides mediated by camphor-derived sulfur ylides: Rationale of enantioselectivity, scope, and limitation

By a sidearm approach, camphor-derived sulfur ylides 1 were designed and synthesized for the cyclopropanation of electron-deficient alkenes and epoxidation of aldehydes. Under the optimal conditions, the exo-type sulfonium salts 4a and 4b reacted with β-a

A novel chiral sulfonium yilde: Highly enantioselective synthesis of vinylcyclopropanes

A newly designed chiral sulfonium allylide, generated in situ from the corresponding sulfonium salt in the presence of KOBut, reacted with α,β-unsaturated esters, ketones, amides, and nitriles to afford trans-2-silylvinyl-trans-3-substituted cy