84673-88-1 Usage
Description
(E)-3-bromo-1-(trimethylsilyl)propene, also known as TMSPM, is an organosilicon compound with the molecular formula C6H13BrSi. It is a colorless liquid characterized by a pungent odor and high reactivity due to its bromine and trimethylsilyl functional groups. TMSPM is recognized for its versatility as a building block in the synthesis of a wide range of organic compounds, including pharmaceuticals and agrochemicals.
Uses
Used in Organic Synthesis:
(E)-3-bromo-1-(trimethylsilyl)propene is used as a reagent for the synthesis of various organic compounds, leveraging its reactivity and the presence of functional groups that facilitate numerous chemical reactions.
Used in Pharmaceutical Synthesis:
In the pharmaceutical industry, (E)-3-bromo-1-(trimethylsilyl)propene is used as a key intermediate in the development of new drugs, contributing to the creation of novel medicinal compounds with potential therapeutic applications.
Used in Agrochemical Synthesis:
Similarly, in the agrochemical sector, (E)-3-bromo-1-(trimethylsilyl)propene serves as a vital component in the synthesis of chemicals used in agriculture, such as pesticides and fertilizers, to enhance crop protection and yield.
Used in the Preparation of Functionalized Silanes:
(E)-3-bromo-1-(trimethylsilyl)propene is also utilized in the preparation of functionalized silanes, which are important in various industrial applications, including materials science and surface modification.
Used as a Protective Group in Organic Chemistry:
In organic chemistry reactions, (E)-3-bromo-1-(trimethylsilyl)propene acts as a protective group for alcohols and amines, preventing unwanted side reactions and ensuring the selective formation of desired products.
Overall, (E)-3-bromo-1-(trimethylsilyl)propene is a valuable compound in the fields of research and industry, with applications spanning across pharmaceuticals, agrochemicals, materials science, and more, due to its unique reactivity and functional group versatility.
Check Digit Verification of cas no
The CAS Registry Mumber 84673-88-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,4,6,7 and 3 respectively; the second part has 2 digits, 8 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 84673-88:
(7*8)+(6*4)+(5*6)+(4*7)+(3*3)+(2*8)+(1*8)=171
171 % 10 = 1
So 84673-88-1 is a valid CAS Registry Number.
84673-88-1Relevant articles and documents
ENANTIOSELECTIVE SYNTHESIS OF THE NAGILACTONE RING SYSTEM VIA VINYLSILANE-MEDIATED POLYENE CYCLIZATION.
Burke, Steven D.,Strickland, Sharon M. S.,Organ, Helen M.,Silks, Louis A.
, p. 6303 - 6306 (1989)
The functionalized tricyclic nagilactone precursor 19 was synthesized by a route featuring a vinylsilane terminated/1,3-dioxane acetal initiated bicyclization.Relative and absolute stereochemical control were achieved via the optically active pentenolide template 14.
Expedient access to branched allylic silanes by copper-catalysed allylic substitution of linear allylic halides
Vyas, Devendra J.,Oestreich, Martin
supporting information; experimental part, p. 568 - 570 (2010/05/01)
An unprecedented copper-catalysed allylic transposition enables the regioselective synthesis of branched allylic silanes from linear allylic halides through direct C-Si bond formation.
A convenient and stereoselective synthesis of trimethylsilylvinyl oxiranes via silylated telluronium allylide+
Zhou,Huang,Shi
, p. 5827 - 5830 (2007/10/02)
Trimethylsilylated diisobutyltelluronium allylide, a moderately stabilized telluronium ylide, generated from 3-trimethylsilyl-2-propenyldiisobutyltelluronium bromide (3) with LiTMP, reacted with carbonyl compounds to afford trimethylsilylvinyl oxiranes in excellent yields with high syn stereoselectivity.
