41725-95-5Relevant academic research and scientific papers
A novel cis-selective cyclohexanone annulation as the key step of a total synthesis of the sesquiterpene lsoacanthodoral
Hampel, Thomas,Brueckner, Reinhard
, p. 4842 - 4845 (2009)
Isoacanthodoral (1) Is a structurally unique sesquiterpene in that it is a bicyclo[4.4.0]dec-1-ene with a cis- rather than the common transjunction between the constituting rings. An efficient construction of this motif has been accomplished by a novel ci
Synthesis based on cyclohexadienes. Part 23. Total synthesis of 5-epi-pupukean-2-one
Kaliappan, Krishna,Subba Rao
, p. 3387 - 3392 (2007/10/03)
A new strategy for the construction of the isotwistane skeleton is reported from easily available cyclohexadienes which involves stereoselective alkylation of a bicyclooctenone derivative and a decarboxylative 5-exo-trig radical cyclisation as the key ste
