41746-22-9

Upstream product

• 75-21-8 oxirane 
• 38203-73-5 C₄H₇BrMg 
• 15232-76-5 oct-3-yne 

Downstream Products

• 69668-89-9 (Z)-2-hydroxy-3-octene 
• 18402-82-9 (3E)-oct-3-en-2-one 
• 33665-27-9 oct-4-en-2-one 
• 850194-93-3 N-(oct-3-yn-2-yl)-N-benzylamine 
• 850194-64-8 (E)-α-(1-chloropentylidene)-β-methyl-N-benzyl-β-lactam 
• 849728-65-0 N-ethyl-α-[1-(1-propenylidene)pentyl]benzenemethanamine 
• 849728-35-4 N-ethyl-N-[1-phenyl-2-(1-propenylidene)hexyl]carbamic acid 1,1-dimethylethyl ester 
• 217187-37-6 2-<((+/-)-2-hydroxyphenyl)thio>oct-3-yne 
• 17257-80-6 Z-3,4-epoxy-2-octanone 
• 20125-81-9 (E)-oct-2-en-4-ol 

Relevant academic research and scientific papers

Oxygenation of alkynes to α,β-acetylenic ketones with dioxygen catalyzed by N-hydroxyphthalimide combined with a transition metal

Alkynes were successfully converted into α,β-acetylenic carbonyl compounds through radical-catalyzed aerobic oxidation using N-hydroxyphthalimide (NHPI) combined with a transion metal under mild conditions.

Syntheses of Monounsaturated Sex Pheromones of Lepidoptera via 3-Alkyn-1-ols

3-Alkyn-1-ols as intermediate synthons in the preparation of some Lepidoteran sex pheromones were utilized.Characteristic fragmentations reflecting the position of the triple bond were found in the mass spectra of 3-alkyn-1-ols and alkyn-1-yl acetates in contrast to 1-tert-butoxy-alkynes.A partial isomerization of 1-tosyloxy-3-(Z)-octene to 1-bromo-3-(E)-octene within the reaction with NaBr in DMF was noticed by GC and 13C-n.m.r., for which a mechanism involving homoconjugation in an intermediate non-classical carbonium ion was suggested.