15232-76-5

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 24, p. 840, 1959 DOI: 10.1021/jo01088a029

InChI:InChI=1/C8H14/c1-3-5-7-8-6-4-2/h3-5,7H2,1-2H3

Upstream product

• 109-65-9 1-bromo-butane 
• 1066-26-8 sodium acetylide 
• 64-67-5 diethyl sulfate 
• 42332-01-4 sodium butylacetylide 
• 14919-01-8 (E)-3-octene 
• 61685-28-7 1-bromo-oct-3-yne 
• 74-96-4 ethyl bromide 
• 693-02-7 hex-1-yne 
• 145074-79-9 8-Bromo-oct-3-yne 
• 7726-95-6 bromine 
• 82166-21-0 methyl cyclohexane 
• 32359-01-6 hexenylmagnesium bromide 

Downstream Products

• 14850-22-7 cis-3-octene 
• 14919-01-8 (E)-3-octene 
• 629-05-0 n-octyne 
• 111-65-9 octane 
• 100243-75-2 C₈H₁₄⁽²⁾H₂ 
• 13721-54-5 Vinylethylacetylen 
• 2384-73-8 hept-1-en-3-yne 
• 17679-92-4 oct-1-en-3-yne 
• 6124-59-0 1-(3-propyl-oxiranyl)-propan-1-one 
• 22286-99-3 (E)-2-octen-4-one 
• 119163-22-3 1-(3-Methyl-oxiranyl)-pentan-1-one 
• 802294-64-0 propionic acid 
• 109-52-4 valeric acid 
• 34214-00-1 (E)-3-Methyl-3-octen 

Relevant academic research and scientific papers

Carbocycle Formation via Intramolecular Insertion of Alkynes into Titanium-Carbon Bonds

Treatment of alkyl titanocene chloride complexes with the Lewis acids EtAlCl2 or Me2AlCl resulted in intramolecular insertion of a tethered alkyne into the Ti-C bond.Regioselective alkyne insertion produced exocyclic trisubstituted alkene products resulting from four-, five-, and six-membered ring formation.In the case of cyclohexane formation, the alkyne was found to insert with syn stereoselectivity.

Selective Synthesis of Alkynes by Catalytic Dehydrogenation of Alkenes over Polymer-supported Palladium Acetate in the Liquid Phase

A heterogenized palladium acetate catalyst, in the presence of oxygen and perchloric acid in ethanol-water caused the direct conversion of terminal and internal monoalkenes into the corresponding alkynes, under mild conditions and in high yields; Wacker-type ketonization occurs with the same reagents in dioxane-water.