15232-76-5 Usage
Synthesis Reference(s)
The Journal of Organic Chemistry, 24, p. 840, 1959 DOI: 10.1021/jo01088a029
Check Digit Verification of cas no
The CAS Registry Mumber 15232-76-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,5,2,3 and 2 respectively; the second part has 2 digits, 7 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 15232-76:
(7*1)+(6*5)+(5*2)+(4*3)+(3*2)+(2*7)+(1*6)=85
85 % 10 = 5
So 15232-76-5 is a valid CAS Registry Number.
InChI:InChI=1/C8H14/c1-3-5-7-8-6-4-2/h3-5,7H2,1-2H3
15232-76-5Relevant articles and documents
Carbocycle Formation via Intramolecular Insertion of Alkynes into Titanium-Carbon Bonds
Harms, Arthur E.,Stille, John R.
, p. 6565 - 6568 (2007/10/02)
Treatment of alkyl titanocene chloride complexes with the Lewis acids EtAlCl2 or Me2AlCl resulted in intramolecular insertion of a tethered alkyne into the Ti-C bond.Regioselective alkyne insertion produced exocyclic trisubstituted alkene products resulting from four-, five-, and six-membered ring formation.In the case of cyclohexane formation, the alkyne was found to insert with syn stereoselectivity.
