41897-46-5

Upstream product

• 28170-13-0 thiobenzoic acid potassium salt 
• 4137-34-2 methyl 2,3,6-tri-O-benzoyl-4-O-methylsulphonyl-α-D-galactopyranoside 
• 13264-02-3 methyl 2,3,6-tri-O-benzoyl-4-S-cyano-4-thio-α-D-glucopyranoside 
• 79580-70-4 Methyl 2,3,6-tri-O-benzoyl-4-O-trifluoromethanesulfonyl-α-D-galactopyranoside 
• 3601-36-3 methyl 2,3,6-tri-O-benzoyl-α-D-galactopyranoside 
• 98-88-4 benzoyl chloride 
• 118868-80-7 methyl 2,3,6-tri-O-benzoyl-4-thio-α-D-glucopyranoside 

Downstream Products

• 149065-24-7 methyl 4-S,6-O-benzylidene-4-thio-α-D-glucopyranoside 
• 149065-25-8 methyl 4-S,6-O-benzylidene-2,3-di-O-mesyl-4-thio-α-D-glucopyranoside 
• 149065-30-5 methyl 4-S-benzyl-2-deoxy-6-O-(p-tolylsulfonyl)-4-thio-α-D-ribo-hexopyranoside 
• 149065-26-9 methyl 2,3-anhydro-4-S,6-O-benzylidene-4-thio-α-D-allopyranoside 
• 149065-27-0 methyl 4-S,6-O-benzylidene-2-deoxy-4-thio-α-D-ribo-hexopyranoside 
• 149065-28-1 methyl 4-S-benzyl-2-deoxy-4-thio-α-D-ribo-hexopyranoside 
• 149065-31-6 methyl 4-S-benzyl-2,6-dideoxy-4-thio-α-D-ribo-hexopyranoside 

Relevant academic research and scientific papers

Synthesis of Methyl 2,6-Dideoxy-4-thio-α-D-ribo-hexopyranoside (Methyl 4-Thiodigitoxoside) - a Constituent of the Calicheamicins and Esperamicins

The 4-thio analog of 2,6-dideoxy-D-ribo-hexopyranose (D-digitoxose) is part of the saccharide chain of the calicheamicins and esperamicins.A straightforeward synthesis of the 4-thiodigitoxoside 12 as its diacetate 13 starting from methyl α-D-galactopyrano

SYNTHESIS OF THIOLACTOSE (4-S-β-D-GALACTOPYRANOSYL-4-THIO-D-GLUCOPYRANOSE)

The potential enzyme-inducer, 4-S-β-D-galactopyranosyl-4-thio-D-glucopyranose, thiolactose (20), was synthesized via two routes.The intermediate, methyl 2,3,6-tri-O-benzoyl-4-S-cyano-4-thio-α-D-glucopyranoside (5), was obtained in high yield from methyl α