41908-42-3Relevant academic research and scientific papers
Perylene derivatives formation in reaction of 3-bromobenzanthrone and 4-bromonaphthalic acid derivatives with a reduction system NiCl2 - 2,2′bipyridyl (or 1,10-phenathroline) - Zn
Adonin,Ryabinin,Starichenko
, p. 861 - 865 (2007/10/03)
The reaction of 3-bromobenzanthrone and 4-bromonaphthalic acid derivatives with a reduction system NiCl2-2,2′bipyridyl (or 1,10-phenathroline)-Zn gives rise to compounds containing perylene fragment. Under similar conditions was established a possibility to transform substituted 1,1′-binaphthyls into the corresponding perylene derivatives.
Reaction of substituted 5-bromoacenaphthenes with the catalytic reduction system NiCl2-2,2'-bipyridyl (or 1,10-phenanthroline)-Zn
Adonin,Ryabinin,Starichenko
, p. 913 - 915 (2007/10/03)
Transformations of substituted 5-bromoacenaphthenes under the action of a catalytic reduction system NiCl2-2,2'-bipyridyl (or 1,10-phenanthrolyne)-Zn in DMF and DMA was studied. Two types of transformation are shown to be characteristic for the studied compounds: reductive coupling with formation of the corresponding 5,5'-biacenaphthenyl and halogen elimination with hydrogen replacing the halogen. Yields of the coupling products and that of dehalogenation are found to depend substantially on the nature of the substituents in the nanhfhalene ring.
