4193-70-8

Usage

Explanation

The molecular formula represents the number of atoms of each element present in a molecule of the compound.

Explanation

1,4-Benzenedicarbonitrile, 2-nitrois a nitro derivative of benzenedicarbonitrile, which means it has a nitro group (-NO2) attached to the benzene ring.

Explanation

The compound appears as a yellow-colored crystalline solid in its pure form.

Explanation

The compound is used as a starting material for the synthesis of a wide range of industrial chemicals and pharmaceuticals.

Explanation

1,4-Benzenedicarbonitrile, 2-nitroserves as a precursor in the synthesis of various dyes, pigments, and other organic compounds due to its reactive functional groups.

Explanation

The compound is also utilized as an intermediate in the production of pesticides and pharmaceuticals, indicating its importance in the chemical industry.

Explanation

Due to its unique chemical properties, 1,4-Benzenedicarbonitrile, 2-nitrohas been studied for its potential applications in organic synthesis and material science, which could lead to the development of new materials and chemical processes.

Explanation

The presence of nitro (-NO2) and cyano (-CN) groups in the molecule makes 1,4-Benzenedicarbonitrile, 2-nitrohighly reactive, allowing it to participate in various chemical reactions and form a wide range of products.

Nitro derivative

Benzenedicarbonitrile

Color and physical state

Yellow crystalline powder

Industrial applications

Production of various industrial chemicals and pharmaceuticals

Precursor in synthesis

Dyes, pigments, and other organic compounds

Intermediate in production

Pesticides and pharmaceuticals

Potential applications

Organic synthesis and material science

Reactivity

Reactive functional groups

Upstream product

• 623-26-7 terephthalonitrile 
• 7697-37-2 nitric acid 
• 13435-20-6 tetraethylammoniumcyanide 
• 619-24-9 3-nitrobenzonitrile 
• 17178-92-6 Nitroterephthalsaeuredichlorid 
• 610-29-7 2-nitroterephthalic acid 
• 50739-80-5 2-nitrobenzene-1,4-dicarboxamide 

Downstream Products

• 27391-37-3 2-aminoterephthalonitrile 
• 51762-73-3 phenylthioterephthalonitrile 
• 51762-74-4 p-Chlorophenylthioterephthalonitrile 
• 51762-79-9 2-(p-ethylphenylthio)terephthalic acid 
• 42946-44-1 diphenylether-2,5,4'-tricarbonitrile 
• 51798-25-5 p-methoxyphenylthioterephthalonitrile 
• 51762-76-6 2-(p-tolylthio)terephthalonitrile 
• 63069-51-2 2-Carbamoyl-5-cyanoanilin 

Relevant academic research and scientific papers

Water-induced fluorescence quenching of mono- and dicyanoanilines

Photophysical properties of monocyano- (2-, 3-, and 4-cyano) and dicyano- (3,4-, 3,5-, 2,3-, 2,4-, 2,5-, and 2,6-dicyano) anilines are investigated by fluorescence measurements. All the monocyanoanilines are virtually nonfluorescent in water (quantum yield 0.01); however, in nonaqueous solvents (cyclohexane, acetonitrile and ethanol), the fluorescence quantum yield is enhanced substantially. In contrast, dicyanoanilines investigated are highly fluorescent both in aqueous and nonaqueous environments. The photophysical data and MO calculations suggest that conformational changes in the amino group and variation of hydrogen-bonding interactions between the solute and solvent water upon electronic excitation are responsible for the water quenching in the monocyanoanilines.

Nitration of moderately deactivated arenes with nitrogen dioxide and molecular oxygen under neutral conditions. Zeolite-induced enhancement of regioselectivity and reversal of isomer ratios

In the presence of zeolites, moderately deactivated arenes such as 1-nitronaphthalene, naphthonitriles, and methylated benzonitriles can be smoothly nitrated at room temperature by the combined action of nitrogen dioxide and molecular oxygen. The regioselectivity is considerably improved as compared with the conventional nitration methodology based on nitric and sulfuric acids. In some cases, the minor isomer became favoured to a significant extent, resulting in the reversal of ordinary isomer ratios of nitration products.

Nucleophilic aromatic substitution for heteroatoms: An oxidative electrochemical approach

The nucleophilic aromatic substitution for heteroatom through electrochemical oxidation of the intermediate σ-complexes (Meisenheimer complexes) in simple nitroaromatic compounds is reported for the first time (NASX process). The studies have been carried out with hydride, cyanide, fluoride, methoxy, and ethanethiolate anions and n-butylamine as a nucleophile, at the cyclic voltammetry (CV) and preparative electrolysis level. The cyclic voltammetry experiments allow for detection and characterization of the σ-complexes and they have led us to a proposal for the mechanism of the oxidation step. Furthermore, the power of the CV technique in the analysis of the reaction mixture throughout the whole chemical and electrochemical process is described.

Nucleophilic aromatic substitution of hydrogen: A novel electrochemical approach to the cyanation of nitroarenes

The nucleophilic aromatic substitution of hydrogen through electrochemical oxidation of the intermediate σ complexes (Meisenheimer complexes) in simple nitroaromatic compounds is reported for the first time. The studies have been carried out with hydride and cyanide anions as the nucleophiles using cyclic voltammetry (CV) and preparative electrolysis. The cyclic voltammetry experiments allow for the detection and characterization of the σ complexes and led us to a proposal for the mechanism of the oxidation step. Furthermore, the power of the CV technique in the analysis of the reaction mixture throughout the whole chemical and electrochemical process is described.