41955-34-4Relevant academic research and scientific papers
The chromium Reformatsky reaction: Access to adjacent quarternary centers
Wessjohann, Ludger,Wild, Harry
, p. 512 - 514 (2007/10/03)
α-Bromo ketones, -esters and -nitriles react with chromium dichloride and ketones in a Barbier-type reaction to yield the kinetic crossed aldol products with one or two new quarternary centers. The reaction does not require special activation of the reage
REFORMATSY TYPE REACTION BY MEANS OF Bu3SnAlEt2 or Bu3PbAlEt2
Tsuboniwa, Noriyuki,Matsubara, Seijiro,Morizawa, Yoshitomi,Oshima, Koichiro,Nozaki, Hitosi
, p. 2569 - 2572 (2007/10/02)
Treatment of α-halo carbonyl compounds with title Sn-Al or Pb-Al reagents provides enolates which react with aldehydes or ketones to give β-hydroxy carbonyl compounds effectively.
