419581-64-9 Usage
Uses
Najera Catalyst II (CAS# 419581-64-9) is an organometallic catalyst used for various cross-couplings reactions such as the Heck-Matsuda reaction of arenediazonium salts and the Suzuki-Miyaura cross-coupling reaction of aryl bromides. Najera Catalyst II has also been used in the catalytic rearrangement and dehydration of aldoximes.
Check Digit Verification of cas no
The CAS Registry Mumber 419581-64-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 4,1,9,5,8 and 1 respectively; the second part has 2 digits, 6 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 419581-64:
(8*4)+(7*1)+(6*9)+(5*5)+(4*8)+(3*1)+(2*6)+(1*4)=169
169 % 10 = 9
So 419581-64-9 is a valid CAS Registry Number.
InChI:InChI=1/2C8H8NO2.2ClH.2Pd/c2*1-6(9-11)7-2-4-8(10)5-3-7;;;;/h2*2,4-5,10-11H,1H3;2*1H;;/q;;;;2*+1/p-2/b2*9-6+;;;;/r2C8H8ClNO2Pd/c2*1-5(10-12)7-3-2-6(11)4-8(7)13-9/h2*2-4,11-12H,1H3/b2*10-5+
419581-64-9Relevant articles and documents
Catalytic activity of palladium supported on single wall carbon nanotubes compared to palladium supported on activated carbon: Study of the Heck and Suzuki couplings, aerobic alcohol oxidation and selective hydrogenation
Corma, Avelino,Garcia, Hermenegildo,Leyva, Antonio
, p. 97 - 105 (2005)
Nanoparticles (2-10 nm) of palladium have been deposited on single wall carbon nanotubes (SWNT) by spontaneous reduction from Pd(OAc)2 or from oxime carbapalladacycle. These catalysts exhibit higher catalytic activity than palladium over activa
