419581-64-9

Usage

Uses

1. Used in [Application Industry]:
a. DI-U-CHLOROBIS(5-HYDROXY-2-(1-(HYDROXYI& is used as [application type] for [application reason].
b. It may also be used as [another application type] for [another application reason].
2. Used in [Another Application Industry]:
a. In this industry, DI-U-CHLOROBIS(5-HYDROXY-2-(1-(HYDROXYI& is used as [different application type] for [different application reason].

InChI:InChI=1/2C8H8NO2.2ClH.2Pd/c2*1-6(9-11)7-2-4-8(10)5-3-7;;;;/h2*2,4-5,10-11H,1H3;2*1H;;/q;;;;2*+1/p-2/b2*9-6+;;;;/r2C8H8ClNO2Pd/c2*1-5(10-12)7-3-2-6(11)4-8(7)13-9/h2*2-4,11-12H,1H3/b2*10-5+

Upstream product

• 34523-34-7 4-hydroxyacetophenone oxime 
• 127-09-3 sodium acetate 

Relevant academic research and scientific papers

Catalytic activity of palladium supported on single wall carbon nanotubes compared to palladium supported on activated carbon: Study of the Heck and Suzuki couplings, aerobic alcohol oxidation and selective hydrogenation

Nanoparticles (2-10 nm) of palladium have been deposited on single wall carbon nanotubes (SWNT) by spontaneous reduction from Pd(OAc)2 or from oxime carbapalladacycle. These catalysts exhibit higher catalytic activity than palladium over activa

Cross-coupling reactions with boronic acids in water catalysed by oxime-derived palladacycles

Palladacycles derived from phenone-oximes 1 are efficient precatalysts for the Suzuki-Miyaura coupling of arylboronic acids with aromatic and heteroaromatic bromides and chlorides under water reflux under aerobic conditions. Alternatively, the coupling can also be carried out at room temperature in methanol-water. Aryl bromides gave biaryls with TON up to 105 and TOF up to 7 × 104 h-1. Activated and deactivated aryl chlorides need the presence of TBAB for the couplings, showing slightly lower efficiency (TON up to 9000 and TOF up to 3850 h-1). C(sp2)-C(sp3) bonds can also be formed by cross-coupling reactions of trimethylboroxine and butylboronic acid with aromatic bromides and chlorides under water reflux and of benzylic and allylic chlorides or acetates with arylboronic acids in acetone-water at room temperature.