41969-01-1Relevant academic research and scientific papers
Iridium cooperation compound as near-infrared light-emitting material, and applications thereof
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Paragraph 0030-0036, (2020/03/02)
The invention relates to an iridium cooperation compound as a near-infrared light-emitting material, wherein the iridium cooperation compound has a nitrogen-containing aromatic condensed ring structure, and an electron-withdrawing cyano group is introduce
A simple and efficient approach toward deep-red to near-infrared-emitting iridium(iii) complexes for organic light-emitting diodes with external quantum efficiencies of over 10%
Chen, Shuming,Chen, Zhao,Wen, Dawei,Wong, Wai-Yeung,Wu, Wenhai,Zeng, Qingguang,Zhang, Hongyang
, p. 2342 - 2349 (2020/03/19)
While the external quantum efficiency (EQE) of iridium(iii) (Ir(iii)) phosphor based near-infrared organic light-emitting diodes (NIR OLEDs) has been limited to 5.7% to date, there is no significant EQE improvement for these types of OLEDs due to the lack
Isoquinoline derivatives, pharmaceutical formulations based on these compounds and the use thereof
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, (2008/06/13)
Isoquinoline-4-carboxylic acid derivatives of the formula I STR1 in which m, n, R1, R2, R3, A and X have the meansings indicated, and physiologically acceptable acid addition salts thereof, a process for their preparation, pharmaceutical formulations based on these compounds and the use thereof as antiarrythmic agents.
Quinoxalines. XXII. Aryl Migration of 2-Aroylquinoxalines to 2-Arylquinoxalines
Higashino, Takeo,Takemoto, Masumi,Tanji, Ken-Ichi,Iijima, Chihoko,Hayashi, Eisaku
, p. 4193 - 4201 (2007/10/02)
The reaction of 2-aroylquinoxalines (1) with sodium hydroxide in dimethyl sulfoxide (DMSO) was found to result in aryl migration, fission of the C2-C=O bond, and addition of DMSO to the C=O group, giving 2-arylquinoxalines (2), quinoxaline (4), aroic acids (5), and α-aryl-α-(methylsulfinylmethyl)-2-quinoxalinemethanols (6).Compounds 6 could be separatedinto two racemates, (αR*,SR*)-6, and (αR*,SS*)-6.In order to establish the generality of the aryl migration, other aroylated aromatic heterocycles were examined. 3-Aroylpyridopyrazines (7) and 1-benzoyl-4-isoquinolinecarbonitrile (10) both underwent similar aryl migration to give 3-arylpyridopyrazines (14) and 1-phenyl-4-isoguinolinecarbonitrile (18), respectively.On the other hand, the reaction of 1-benzoylisoquinoline (9) and 2-benzoilquinoline (11) resulted not in migration, but in the addition of DMSO to give 1-isoquinolinemethanol (16) and 2-quinolinemethanol derivatives (20), respectively.In the case of 1-benzoylphtalazine (8), migration did not occur, but instead 4-benzoyl-1(2H)-phthalazinone (15) was formed.Keywords - 2-aroylquinoxaline; 2-arylquinoxaline; 2-quinoxalinemethanol; aryl migration; racemate; 3-arylpyridopyrazine; 1-isoquinolinemethanol; 2-quinolinemethanol; 1-phenyl-4-isoquinolinecarbonitrile; 4-benzoyl-1(2H)-phthalazinone
