420-97-3Relevant articles and documents
PROCESSES FOR PRODUCING 2-CHLORO-1,1,1,2-TETRAFLUOROPROPANE AND 2,3,3,3-TETRAFLUOROPROPENE
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Page/Page column 5, (2011/10/12)
To provide processes for efficiently and economically producing 2-chloro-1,1,1,2-tetrafluoropropane (R244bb) and 2,3,3,3-tetrafluoropropene (R1234yf) in an industrially practical manner. A process for producing 2-chloro-1,1,1,2-tetrafluoropropane, which comprises a chlorination step of reacting 1,2-dichloro-2-fluoropropane and chlorine in the presence of a solvent under irradiation with light to obtain 1,1,1,2-tetrachloro-2-fluoropropane, and a fluorination step of reacting the 1,1,1,2-tetrachloro-2-fluoropropane obtained in the chlorination step and hydrogen fluoride in the presence of a catalyst to obtain 2-chloro-1,1,1,2-tetrafluoropropane, and a process for producing 2,3,3,3-tetrafluoropropene, which comprises dehydrochlorinating it in the presence of a catalyst.
REACTION OF ALKANES, ETHERS AND ALIPHATIC KETONES WITH THE SF4-HF-Cl2 SYSTEM
Muratov, N. N.,Omarov, V. O.,Kunshenko, B. V.,Burmakov, A. I.,Alekseeva, L. A.,Yagupol'skii, L. M.
, p. 1621 - 1626 (2007/10/02)
The reaction of alkanes, ethers, and aliphatic ketones with the SF4-HF-Cl2 system takes place through formation of unsaturated compounds followed by addition of the chloride and fluoride ions.The presence of sulfur tetrafluoride in the rection mixture pro