42003-39-4

Basic information

• Product Name: CHLOROMETHYLSILATRANE
• Synonyms: CHLOROMETHYLSILATRANE;1-(Chloromethyl)-2,8,9-trioxa-5-aza-1-silabicyclo(3.3.3)undecane;1-(chloromethyl)-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane;1-(Chloromethyl)silatrane;1-Chloromethyl-2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3]undecane;2,8,9-trioxa-5-aza-1-silabicyclo(3.3.3)undecane,1-(chloromethyl);2,8,9-Trioxa-5-aza-1-silabicyclo[3.3.3]undecane,1-(chloromethyl)-;9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane,1-(chloromethyl)-8
• CAS NO: 42003-39-4
• Molecular Formula: C₇H₁₄ClNO₃Si
• Molecular Weight: 223.73
• EINECS: 255-621-1
• Mol File: 42003-39-4.mol
• Article Data: 8

Chemical Properties

• Melting Point: 221 °C
• Boiling Point: 263.1 °C at 760 mmHg
• Flash Point: 112.9 °C
• Appearance: /
• Density: 1.24 g/cm³
• Vapor Pressure: 0.0105mmHg at 25°C
• Refractive Index: 1.501
• CAS DataBase Reference: CHLOROMETHYLSILATRANE(CAS DataBase Reference)
• NIST Chemistry Reference: CHLOROMETHYLSILATRANE(42003-39-4)
• EPA Substance Registry System: CHLOROMETHYLSILATRANE(42003-39-4)

Safety Data

• TSCA: Yes
• Hazardous Substances Data: 42003-39-4(Hazardous Substances Data)

Usage

General Description

Chloromethylsilatrane is a chemical compound that contains a silicon atom bonded to multiple organic groups and a chlorine atom. It is used in the synthesis of various silicon-containing compounds and has applications in the field of organic chemistry. Chloromethylsilatrane is known for its ability to form strong carbon-silicon bonds, making it useful for cross-coupling reactions and other organic transformations. CHLOROMETHYLSILATRANE has potential uses in the development of advanced materials and pharmaceuticals due to its unique chemical reactivity and stability. Additionally, it is known for its water repellent properties and may find applications in coatings and surface treatments.

InChI:InChI=1/C7H14ClNO3Si/c8-7-13-10-4-1-9(2-5-11-13)3-6-12-13/h1-7H2

Upstream product

• 102-71-6 triethanolamine 
• 15267-95-5 chloromethyltriethoxysilane 
• 283-56-7 2,8,9-trioxa-5-aza-1-borabicyclo[3.3.3]undecane 
• 1558-25-4 (chloromethyl)trichlorosilane 
• 5926-26-1 (chloromethyl)trimethoxysilane 
• 64-17-5 ethanol 
• 118162-82-6 2-methyl-2-phenyl-6-(2-hydroxyethyl)-1,3,6,2-dioxazasilocane 
• 144967-53-3 2-Methyl-6-(2-trimethylsilanyloxy-ethyl)-2-vinyl-[1,3,6,2]dioxazasilocane 
• 135718-12-6 2,2-dimethyl-6-<2-(trimethylsiloxy)ethyl>-1,3,6,2-dioxazasilocane 
• 20836-42-4 2,2',2''-tris(trimethylsiloxy)triethylamine 

Downstream Products

• 138372-29-9 dimethylphenyl(silatranylmethyl)silane 
• 17305-95-2 (chloromethyl)mercury(II) chloride 
• 102-71-6 triethanolamine 
• 114829-30-0 N-<(1-Silatranyl)methyl>phthalimide 
• 138372-30-2 methyldiphenyl(silatranylmethyl)silane 
• 138372-32-4 (+/-)-(silatranylmethyl)methylphenylsilane 
• 7601-53-8 tris(2-hydroxyethyl)amine hydroiodide 

Relevant articles and documents

Direct synthesis of 1-organylsilatranes from organyltrichlorosilanes and tris(2-hydroxyethyl)amine

A direct method of synthesis of 1-organylsilatranes by the reaction of organyltrichlorosilanes with tris(2-hydroxyethyl)amine was developed. 1-Organylsilatranes RSi(OCH2CH2)3N with R = Me, Et, Ph, ClCH2, ICH2, Cl(CH2)3 were prepared by this method in up to 72% yield.

MEDIUM-SIZED SILICON-CONTAINING RINGS. IV. SILOCANE-SILATRANE TRANSFORMATIONS

We have discovered an intramolecular condensation of trimethylsilyl ethers of silocines with a phenyl substituent on the silicon atom that leads to the corresponding silatranes.For the preparation of N-(hydroxyethy) derivatives of silocines we have, for the first time, used the cyclosilylation of triethanolamine with a bis(dialkylamino)silane.It was found that in the exothermic reaction of trialkoxyalkylsilanes with N-(hydroxyethyl) derivatives of silocines and their trimethylsilyl ethers the yield of silatranes is only slighthly dependent on the nature of the substituent both in the silocines and in the alkoxysilanes.

METHOD FOR THE SYNTHESIS OF SILATRANES

-