4201-63-2Relevant academic research and scientific papers
Borinic acid-catalyzed stereo- and site-selective synthesis of β-glycosylceramides
D'Angelo, Kyan A.,Taylor, Mark S.
supporting information, p. 5978 - 5980 (2017/07/10)
A method for activation of unprotected ceramides towards stereo- and site-selective glycosylation is described. Two-point binding of a diarylborinic acid catalyst to the ceramide accelerates its reactions with 'armed' glycosyl methanesulfonate donors, resulting in the formation of a β-glycosidic linkage at the primary OH group.
Efficient syntheses of a series of glycosphingolipids with 1,2-trans-glycosidic linkages
Liu, Yunpeng,Ding, Ning,Xiao, Hualing,Li, Yingxia
, p. 471 - 489 (2007/10/03)
A series of glycosphingolipids with 1,2-trans-glycosidic linkages were synthesized in the presence of neighboring group participation using trichloroacetimidates as glycosyl donors and an azido-sphingosine as the glycosyl acceptor. During the preparation
