420119-94-4

Upstream product

• 1129-30-2 2,6-Diacetylpyridine 
• 579-66-8 2,6-diethylaniline 

Downstream Products

• 500117-12-4 (2,6-bis[1-((2,6-diethylphenyl)imino)ethyl]pyridine)trichlorochromium(III) 
• 1246673-13-1 RhCl[2,6-bis(1-(2,6-diethylphenyl)iminoethyl)pyridine] 
• 845863-63-0 C₂₉H₃₅Cl₃N₃V 
• 1165950-34-4 [HgCl₂(2,6-bis(1-(2,6-diethylphenylimino)ethyl)pyridine)]*acetonitrile 
• 863328-55-6 iron(II)(bis(2,6-Et₂-phenyl-iminomethyl)pyridine)(CH₂SiMe₃)2 
• 257933-26-9 2,6-bis-[1-(2,6-diethylphenylimino)ethyl]pyridine iron(II) chloride 

Relevant academic research and scientific papers

Earth-Abundant Metal Catalysis Enabled by Counterion Activation

A precatalyst activation strategy has been developed for earth-abundant metal catalysis enabled by counterion dissociation and demonstrated through alkene hydroboration. Commercially available iron and cobalt tetrafluoroborate salts were found to catalyze

Electronic Effects of the Backbone on Bis(imino)pyridyliron(II)-Catalyzed Ethylene Polymerization

A series of bis(imino)pyridyl iron(II) complexes 1–5 with electron-donating and -withdrawing substituents on the backbone of the ligand have been synthesized and characterized. Activated with methylaluminoxane (MAO), ethylene polymerization by these iron(

Mechanochemical routes for the synthesis of acetyl- A nd bis-(imino)pyridine ligands and organometallics

Organometallic precatalysts play a pivotal role in organic synthesis. However, their preparation often relies on multiple time, energy, and solvent intensive steps, including the synthesis of supporting organic ligand structures, and finally installation

Amine-Activated Iron Catalysis: Air- and Moisture-Stable Alkene and Alkyne Hydrofunctionalization

A simple alkylamine [(iPr)2NEt] has been used to activate an air- and moisture-stable iron(II) pre-catalyst for alkene and alkyne hydrofunctionalization reactions. This amine activation has enabled the highly operationally simple hydrosilylatio

Iron-catalysed chemo-, regio-, and stereoselective hydrosilylation of alkenes and alkynes using a bench-stable iron(II) pre-catalyst

The chemo-, regio-, and stereoselective iron-catalysed hydrosilylation of alkenes and alkynes with excellent functional group tolerance is reported (34 examples, 41-96% yield). The catalyst and reagents are commercially available and easy to handle, with the active iron catalyst being generated in situ, thus providing a simple and practical methodology for iron-catalysed hydrosilylation. The silane products can be oxidised to the anti-Markovnikov product of olefin hydration, and the one-pot iron-catalysed hydrosilylation-oxidation of olefins to give silane(di)ols directly is also reported. The iron pre-catalyst was used at loadings as low as 0.07 mol%, and displayed catalyst turnover frequencies (TOF) approaching 60,000 molh-1. Initial mechanistic studies indicate an iron(I) active catalyst.

Chemo-, regio-, and stereoselective iron-catalysed hydroboration of alkenes and alkynes

The highly chemo-, regio-, and stereoselective synthesis of alkyl- and vinyl boronic esters with good functional group tolerance has been developed using in situ activation of a bench-stable iron(ii) pre-catalyst and pinacolborane (16 examples, 45-95% yield, TOF up to 30000 mol h-1). The first iron-catalysed alkene hydrogermylation is also reported.

Enhance the performance of dye-sensitized solar cells by co-sensitization of 2,6-bis(iminoalkyl)pyridine and N719

Three organic dyes 2,6-bis(iminoalkyl)pyridines [2,6-(2,6-R 2C6H2NCMe)2]C5H 3N (R = methyl, ethyl, isopropyl) (named DM, DE and DP, respectively) were synthesized and assembled onto nanocry

Syntheses, structures, and luminescent properties of Zn(II) and Cd(II) complexes: 3-D supramolecules based on 2,6-bis(imino)pyridine ligands constructed by hydrogen bonding interactions

Six 5-coordinate 2,6-bis(imino)pyridine metal complexes, [2,6-(ArN=CMe)2C5H3NMCl2 · nCH3CN] (Ar = 4-MeC6H4, M = Zn, n = 0.5, Zn1, M = Cd, n = 1, Cd1; Ar = 2,6-Et2C6H3, M = Zn, n = 0.5, Zn2, M = Cd, n = 0.5, Cd2; Ar = 2,4,6-Me3C6H2, M = Zn, n = 1, Zn3, M = Cd, n = 1, Cd3), were synthesized in acetonitrile by the reactions of the corresponding bis(imino)pyridines with ZnCl2 or CdCl2 · 2.5H2O, respectively. The structures of Zn1-Zn3 and Cd1-Cd3 were determined by the single-crystal X-ray diffraction. In all complexes, the ligand is tridentate with further coordination by two chlorides, resulting in a distorted trigonal bipyramid. All complexes self-assemble through hydrogen bonding interactions to form a 3-D supramolecular structure. At 298 K in dichloromethane, all complexes have blue luminescent emissions at 405-465 nm, which can be attributed to ligand-centered π* → π transitions. The zinc and cadmium centers play a key role in enhancing fluorescent emission of the ligands.

Syntheses, structures, and luminescent properties of copper(II) complexes based on 2,6-bis(imino)pyridyl ligands

A series of five-coordinated 2,6-bis(imino)pyridyl Cu(II) complexes, [2,6-(ArNCMe)2C5H3NCuCl2· nCH3CN] (Ar = 4-MeC6H4, n = 0.5, Cu1; Ar = 2,6-Et2C6H3/