420119-94-4

Upstream product

• 1129-30-2 2,6-Diacetylpyridine 
• 579-66-8 2,6-diethylaniline 

Downstream Products

• 500117-12-4 (2,6-bis[1-((2,6-diethylphenyl)imino)ethyl]pyridine)trichlorochromium(III) 
• 863328-55-6 iron(II)(bis(2,6-Et₂-phenyl-iminomethyl)pyridine)(CH₂SiMe₃)2 
• 1165950-34-4 [HgCl₂(2,6-bis(1-(2,6-diethylphenylimino)ethyl)pyridine)]*acetonitrile 
• 845863-63-0 C₂₉H₃₅Cl₃N₃V 
• 1246673-13-1 RhCl[2,6-bis(1-(2,6-diethylphenyl)iminoethyl)pyridine] 
• 257933-26-9 2,6-bis-[1-(2,6-diethylphenylimino)ethyl]pyridine iron(II) chloride 

Relevant academic research and scientific papers

Earth-Abundant Metal Catalysis Enabled by Counterion Activation

A precatalyst activation strategy has been developed for earth-abundant metal catalysis enabled by counterion dissociation and demonstrated through alkene hydroboration. Commercially available iron and cobalt tetrafluoroborate salts were found to catalyze

Mechanochemical routes for the synthesis of acetyl- A nd bis-(imino)pyridine ligands and organometallics

Organometallic precatalysts play a pivotal role in organic synthesis. However, their preparation often relies on multiple time, energy, and solvent intensive steps, including the synthesis of supporting organic ligand structures, and finally installation

Electronic Effects of the Backbone on Bis(imino)pyridyliron(II)-Catalyzed Ethylene Polymerization

A series of bis(imino)pyridyl iron(II) complexes 1–5 with electron-donating and -withdrawing substituents on the backbone of the ligand have been synthesized and characterized. Activated with methylaluminoxane (MAO), ethylene polymerization by these iron(

Amine-Activated Iron Catalysis: Air- and Moisture-Stable Alkene and Alkyne Hydrofunctionalization

A simple alkylamine [(iPr)2NEt] has been used to activate an air- and moisture-stable iron(II) pre-catalyst for alkene and alkyne hydrofunctionalization reactions. This amine activation has enabled the highly operationally simple hydrosilylatio

Iron-catalysed chemo-, regio-, and stereoselective hydrosilylation of alkenes and alkynes using a bench-stable iron(II) pre-catalyst

The chemo-, regio-, and stereoselective iron-catalysed hydrosilylation of alkenes and alkynes with excellent functional group tolerance is reported (34 examples, 41-96% yield). The catalyst and reagents are commercially available and easy to handle, with the active iron catalyst being generated in situ, thus providing a simple and practical methodology for iron-catalysed hydrosilylation. The silane products can be oxidised to the anti-Markovnikov product of olefin hydration, and the one-pot iron-catalysed hydrosilylation-oxidation of olefins to give silane(di)ols directly is also reported. The iron pre-catalyst was used at loadings as low as 0.07 mol%, and displayed catalyst turnover frequencies (TOF) approaching 60,000 molh-1. Initial mechanistic studies indicate an iron(I) active catalyst.

Chemo-, regio-, and stereoselective iron-catalysed hydroboration of alkenes and alkynes

The highly chemo-, regio-, and stereoselective synthesis of alkyl- and vinyl boronic esters with good functional group tolerance has been developed using in situ activation of a bench-stable iron(ii) pre-catalyst and pinacolborane (16 examples, 45-95% yield, TOF up to 30000 mol h-1). The first iron-catalysed alkene hydrogermylation is also reported.

Enhance the performance of dye-sensitized solar cells by co-sensitization of 2,6-bis(iminoalkyl)pyridine and N719

Three organic dyes 2,6-bis(iminoalkyl)pyridines [2,6-(2,6-R 2C6H2NCMe)2]C5H 3N (R = methyl, ethyl, isopropyl) (named DM, DE and DP, respectively) were synthesized and assembled onto nanocry

Syntheses, structures, and luminescent properties of Zn(II) and Cd(II) complexes: 3-D supramolecules based on 2,6-bis(imino)pyridine ligands constructed by hydrogen bonding interactions

Six 5-coordinate 2,6-bis(imino)pyridine metal complexes, [2,6-(ArN=CMe)2C5H3NMCl2 · nCH3CN] (Ar = 4-MeC6H4, M = Zn, n = 0.5, Zn1, M = Cd, n = 1, Cd1; Ar = 2,6-Et2C6H3, M = Zn, n = 0.5, Zn2, M = Cd, n = 0.5, Cd2; Ar = 2,4,6-Me3C6H2, M = Zn, n = 1, Zn3, M = Cd, n = 1, Cd3), were synthesized in acetonitrile by the reactions of the corresponding bis(imino)pyridines with ZnCl2 or CdCl2 · 2.5H2O, respectively. The structures of Zn1-Zn3 and Cd1-Cd3 were determined by the single-crystal X-ray diffraction. In all complexes, the ligand is tridentate with further coordination by two chlorides, resulting in a distorted trigonal bipyramid. All complexes self-assemble through hydrogen bonding interactions to form a 3-D supramolecular structure. At 298 K in dichloromethane, all complexes have blue luminescent emissions at 405-465 nm, which can be attributed to ligand-centered π* → π transitions. The zinc and cadmium centers play a key role in enhancing fluorescent emission of the ligands.

Syntheses, structures, and luminescent properties of copper(II) complexes based on 2,6-bis(imino)pyridyl ligands

A series of five-coordinated 2,6-bis(imino)pyridyl Cu(II) complexes, [2,6-(ArNCMe)2C5H3NCuCl2· nCH3CN] (Ar = 4-MeC6H4, n = 0.5, Cu1; Ar = 2,6-Et2C6H3/