42013-62-7

Basic information

• Product Name: 9,10-Anthracenedione, 1-azido-
• CAS NO: 42013-62-7
• Molecular Formula: C14H7N3O2
• Molecular Weight: 249.228
• Mol File: 42013-62-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 9,10-Anthracenedione, 1-azido-(CAS DataBase Reference)
• NIST Chemistry Reference: 9,10-Anthracenedione, 1-azido-(42013-62-7)
• EPA Substance Registry System: 9,10-Anthracenedione, 1-azido-(42013-62-7)

Safety Data

• Hazardous Substances Data: 42013-62-7(Hazardous Substances Data)

Downstream Products

• 2872-47-1 1-amino-4-chloroanthraquinone 
• 82-45-1 1-amino-9,10-anthracenedione 
• 129-43-1 1-hydroxyanthraquinone 
• 81-64-1 1,4-dihydroxy-9,10-anthracenedione 
• 85193-36-8 diphenyl N-(anthraquinon-1-yl)phosphoramidate 
• 85193-21-1 N-(anthraquinon-1-yl)triphenylphosphazene 
• 85193-11-9 1-S,S-diphenyl-N-(anthraquinon-1-yl)sulfoximide 
• 85193-05-1 1-S-methyl-1-S-phenyl-N-(anthraquinon-1-yl)sulfoximide 
• 116-85-8 4-hydroxy-1-aminoanthraquinone 

Relevant articles and documents

Preparation of glycosyltriazenes

O-Unprotected glycosyltriazenes are prepared for the first time by coupling of 1-anthraquinone-1-diazonium hydrogensulfate with β-glycopyranosylamines to afford 1-(anthraquinone-1-yl)-3-(β-glycopyranosyl)triazenes 3a-h. Acetylation of compounds 3 furnished the O-acetates 4a-g. The stability of triazenes 3 results from fixation of the NH proton in an intramolecular hydrogen bond to one of the anthraquinone carbonyl oxgen atoms. Treatment of triazenes 4 with tert-butyl hypochlorite afforded acetoglycosyl chlorides 6 and 1-azidoanthraquinone 7. With acetic acid the triazene 4a formed tetra-O-acetyl-D-xylopyranose 9 together with 1-aminoanthraquinone 10. WIiley-VCH Verlag GmbH, 2000.