4203-45-6Relevant academic research and scientific papers
Bismuth(III) bromide in organic synthesis. A catalytic method for the allylation of tetrahydrofuranyl and tetrahydropyranyl ethers
Krabbe, Scott W.,Angeles, Veronica V.,Mohan, Ram S.
supporting information; experimental part, p. 5643 - 5645 (2010/11/18)
A bismuth bromide-catalyzed (10.0 mol %) multicomponent reaction involving the allylation of THF- and THP-ethers, followed by in situ derivatization with acetic anhydride to generate highly functionalized esters has been developed under solvent-free conditions. To the best of our knowledge, this is the first report of a catalytic procedure for the allylation of THF- and THP-ethers to yield ring-opened products.
REACTIONS OF ALLYLSILANES WITH α-CHLORO ETHERS CATALYZED BY IODOTRIMETHYLSILANE OR TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE. SYNTHESIS OF HOMOALLYL ETHERS
Sakurai, Hideki,Sakata, Yasuyuki,Hosomi, Akira
, p. 409 - 412 (2007/10/02)
Iodotrimethylsilane and trimethylsilyl triflate activate selectively the C-Cl bond rather than the C-O bond of α-chloro ethers and catalyze the allylation with allylsilanes to give the corresponding homoallyl ether effectively in good yield.
