42068-13-3Relevant academic research and scientific papers
A chiral-anion generator: Application to catalytic desilylative kinetic resolution of silyl-protected secondary alcohols
Yan, Hailong,Jang, Hyeong Bin,Lee, Ji-Woong,Kim, Hong Ki,Lee, Soon Won,Yang, Jung Woon,Song, Choong Eui
supporting information; experimental part, p. 8915 - 8917 (2011/02/21)
Getting the grips on fluoride: Chiral hydroxy-terminated polyethers bearing a 3,3′-halogen-substituted chiral 1,1′-bi-2-naphthol (BINOL) unit manifest a new structural motif for chiral-anion generators. Their unique properties are revealed through highly enantioselective desilylative kinetic resolution of a variety of silyl-protected racemic alcohols with KF (see scheme).
