62559-30-2

Basic information

• Product Name: Silane, trimethyl(1-phenylpropoxy)-
• CAS NO: 62559-30-2
• Molecular Formula: C12H20OSi
• Molecular Weight: 208.376
• Mol File: 62559-30-2.mol
• Article Data: 23

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl(1-phenylpropoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl(1-phenylpropoxy)-(62559-30-2)
• EPA Substance Registry System: Silane, trimethyl(1-phenylpropoxy)-(62559-30-2)

Safety Data

• Hazardous Substances Data: 62559-30-2(Hazardous Substances Data)

Upstream product

• 38858-73-0 1-phenyl-1-trimethylsiloxycyclopropane 
• 75-77-4 chloro-trimethyl-silane 
• 93-55-0 1-phenyl-propan-1-one 
• 93-54-9 1-Phenyl-1-propanol 
• 4039-32-1 lithium hexamethyldisilazane 
• 14630-40-1 Bis(trimethylsilyl)ethyne 
• 557-20-0 diethylzinc 
• 100-52-7 benzaldehyde 
• 33861-17-5 phenyl trimethylsilyl selenide 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 

Downstream Products

• 27238-93-3 1-methoxy-4-(1-phenylpropyl)benzene 
• 93-54-9 1-Phenyl-1-propanol 
• 253431-47-9 3-hydroxy-1,4-diphenyl-2-methylbutanone 
• 93250-21-6 3-hydroxy-2-methyl-1-phenyl-hexan-1-one 
• 344349-02-6 3-Cyclohexyl-3-hydroxy-2-methyl-1-phenylpropan-1-one 
• 42068-13-3 C₁₂H₂₀OSi 
• 1228675-03-3 3-hydroxy-2-methyl-3-(4-methylphenyl)-1-phenylbutan-1-one 
• 1228675-01-1 3-hydroxy-1-(4-methylphenyl)-3-phenylpentan-1-one 
• 4426-82-8 (1-isothiocyanatopropyl)benzene 
• 4119-41-9 (±)-(1-iodopropyl)benzene 
• 93-55-0 1-phenyl-propan-1-one 

Relevant articles and documents

Silylation of Alcohols, Phenols, and Silanols with Alkynylsilanes – an Efficient Route to Silyl Ethers and Unsymmetrical Siloxanes

The formation of several silyl ethers (alkoxysilanes, R3Si-OR') and unsymmetrical siloxanes (R3Si-O-SiR'3) can be catalyzed by the commercially available potassium bis(trimethylsilyl)amide (KHMDS). The reaction proceeds via direct dealkynative coupling between various alcohols or silanols and alkynylsilanes, with a simultaneous formation of gaseous acetylene as the sole by-product. The dehydrogenative and dealkenative coupling of alcohols or silanols are well-investigated, whilst the utilization of alkynylsilanes as silylating agents has never been comprehensively studied in this context. Overall, the presented system allows the synthesis of various attractive organosilicon compounds under mild conditions, making this approach an atom-efficient, environmentally benign, and sustainable alternative to existing synthetic solutions.

Fast and efficient method for Silylation of alcohols and phenols with HMDS in the presence of bis-thiourea complexes of cobalt, nickel, copper and zinc chlorides

Bis-thiourea complexes of cobalt, nickel, copper and zinc chlorides were used efficiently for rapid and efficient trimethylsilylation of alcohols and phenols with hexamethyldisilazane (HMDS) in CH3CN. All reactions were carried out at room temperature within immediate-120?min timeframe to afford trimethylsilyl ether derivatives in high to excellent yields. Investigation of the results exhibited that the prepared bis-thiourea metal complexes show the activity as Co(tu)2Cl2> Ni(tu)2Cl2> Cu(tu)2Cl2> Zn(tu)2Cl2 in their silylation reactions.

Rice husk: Introduction of a green, cheap and reusable catalyst for the protection of alcohols, phenols, amines and thiols

A mild, efficient and eco-friendly protocol for the chemoselective protection of benzylic and primary and less hindered secondary aliphatic alcohols and phenols as trimethylsilyl ethers and different types of amines as N-tert-butylcarbamates is developed using rice husk (RiH) as the catalyst. This reagent is also able to catalyze the acetylation of alcohols, phenols, thiols and amines with acetic anhydride. Easy work-up, relatively short reaction times, excellent yields and low cost, availability and reusability of the catalyst are the striking features of this methodology, which can be considered to be one of the best and general methods for the protection of alcohols, phenols, thiols and amines. In addition, the use of a green reagent in the above-mentioned reactions results in a reduction of environmental pollution and of the cost of the applied methods.