42071-66-9Relevant articles and documents
Transition-Metal-Free Reductive Deoxygenative Olefination with CO2
Zhu, Dao-Yong,Li, Wen-Duo,Yang, Ce,Chen, Jie,Xia, Ji-Bao
supporting information, p. 3282 - 3285 (2018/06/11)
A new transition-metal-free reductive deoxygenative olefination of phosphorus ylides with CO2, an abundant and sustainable C1 chemical feedstock, is described. This catalytic CO2 fixation afforded β-unsubstituted acrylates and vinyl ketones in good yields with broad scope and good functional group tolerance under mild reaction conditions. Cost-effective and easily handled polymethylhydrosiloxane was used as a reductant. Bis(silyl)acetal was proved to be the key intermediate in this reductive functionalization of CO2.
Thermal retro-aldol reaction using fluorous ether F-626 as a reaction medium
Fukuyama, Takahide,Kawamoto, Takuji,Okamura, Takahiro,Denichoux, Aurelien,Ryu, Ilhyong
experimental part, p. 2193 - 2196 (2010/10/21)
A high-boiling, fluorous-organic hybrid ether, F-626, was tested for use in thermal retro-aldol reactions and found to be an excellent reaction medium in view of the ease of separation from the product by fluorous/organic biphasic treatment. The recovered F-626 can be readily reused for subsequent runs.
Hydroxymethylation of Propiophenones in Aqueous Medium: A New Route to 1-Aryl-2-methyl-2-propen-1-ones
Curzu, Maria Michela,Pinna, Gerard Aime,Barlocco, Daniela,Bugatti, Carlo,Cignarella, Giorgio
, p. 339 - 342 (2007/10/02)
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