422322-47-2Relevant academic research and scientific papers
Cp*Ru+ complexes of benzylideneaniline and salicylideneaniline
Wheeler, Dale E,Baetz, Nicholas W,Holder, Grant N,Hill, Scott T,Milos, Steven,Luczak, Kraig A
, p. 210 - 217 (2002)
The reaction product of Cp*Ru(CH3CN)3+ OSO2CF3- with salicylaldehyde yielded (1) which reacted with a series of aniline derivatives to produce air-stable solids. These products were characterized by 1H and 13C NMR spectrometry and UV - Vis spectroscopy. Solvatochromism studies of these products revealed that the p-NH2 and p-N(CH3)2 derivatives exhibit relatively large values of molecular hyperpolarizability and have the potential to exhibit nonlinear optical properties. These derivatives were further studied by electrochemical investigations.
