Inorganica Chimica Acta p. 210 - 217 (2002)
Update date:2022-08-05
Topics:
Wheeler, Dale E
Baetz, Nicholas W
Holder, Grant N
Hill, Scott T
Milos, Steven
Luczak, Kraig A
The reaction product of Cp*Ru(CH3CN)3+ OSO2CF3- with salicylaldehyde yielded (1) which reacted with a series of aniline derivatives to produce air-stable solids. These products were characterized by 1H and 13C NMR spectrometry and UV - Vis spectroscopy. Solvatochromism studies of these products revealed that the p-NH2 and p-N(CH3)2 derivatives exhibit relatively large values of molecular hyperpolarizability and have the potential to exhibit nonlinear optical properties. These derivatives were further studied by electrochemical investigations.
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