42277-06-5Relevant academic research and scientific papers
Spirolactams by a novel ipso-radical cyclisation and loss of aromaticity
Boivin, Jean,Yousfi, Mohammed,Zard, Samir Z.
, p. 5985 - 5988 (1997)
Spirolactams are obtained by ipso radical cyclisation when various substituted N-benzyl trichloroacetamides are subjected to the nickel powder/acetic acid reducing system.
Olefin cyclopropanation by a sequential atom-transfer radical addition and dechlorination in the presence of a ruthenium catalyst
Thommes, Katrin,Kiefer, Gregor,Scopelliti, Rosario,Severin, Kay
supporting information; experimental part, p. 8115 - 8119 (2010/01/16)
Without diazo: The reductive coupling of olefins with dichloro compounds in the presence of a ruthenium catalyst and magnesium gives cyclopropanes in good yield (see scheme).
