423151-65-9

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 423151-64-8 (3S,5R,6R)-7-(4-methoxybenzyloxy)-6-methyl-3-vinylheptane-1,5-diol 
• 89238-99-3 O-(4-methoxybenzyl)-trichloroacetimidate 
• 423118-12-1 tert-butyl-diphenyl-(5-vinyloxy-pent-3-enyloxy)-silane 
• 423117-83-3 (2'S,3'R,4R,5S,5'R)-3-{5'-[2''-(tert-butyldiphenylsilanyloxy)-ethyl]-3'-hydroxy-2'-methylhept-6'-enoyl}-4-methyl-5-phenyloxazolidin-2-one 
• 423118-46-1 (2R,3R,5S)-5-[2'-(tert-butyldiphenylsilanyloxy)-ethyl]-1-(4-methoxybenzyloxy)-2-methylhept-6-en-3-ol 
• 423117-81-1 (α)-3-[2-(tert-butyldiphenylsilanyloxy)-ethyl]-pent-4-enal 
• 256494-25-4 (E)-ethyl 5-(2,2-dimethyl-1,1-diphenyl-1-silapropoxy)pent-2-enoate 
• 127665-77-4 (E)-5-(2,2-dimethyl-1,1-diphenyl-1-silapropoxy)pent-2-en-1-ol 
• 423118-38-1 (2R,3R,5S)-5-[2'-(tert-butyldiphenylsilanyloxy)-ethyl]-2-methylhept-6-ene-1,3-diol 

Downstream Products

• 423118-49-4 (3S,5R,6R)-3-[2-(tert-butyldimethylsilanyloxy)-ethyl]-7-(4-methoxybenzyloxy)-6-methylheptane-1,5-diol 
• 423118-33-6 (2R,4'R,6'R)-2-{4'-[2-(tert-butyldiphenylsilanyloxy)-ethyl]-6'-oxo-tetrahydropyran-2'-yl}-propionaldehyde 
• 423118-32-5 (4R,6R)-4-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-6-((R)-1-hydroxypropan-2-yl)tetrahydro-2H-pyran-2-one 
• 423118-16-5 (1'R,4R,6R)-4-[2-(tert-butyldiphenylsilanyloxy)-ethyl]-6-(1'-methylprop-2'-ynyl)-tetrahydropyran-2-one 
• 423118-17-6 (1'R,4R,6R)-4-[2-(tert-butyldiphenylsilanyloxy)-ethyl]-6-[2'-(4-methoxybenzyloxy)-1'-methylethyl]-tetrahydropyran-2-one 
• 423118-18-7 (3R,5R,6R)-3-[2-(tert-butyldiphenylsilanyloxy)-ethyl]-7-(4-methoxybenzyloxy)-6-methylheptane-1,5-diol 
• 423151-67-1 (3S,3R,5R)-5-[2-(tert-butyldimethylsilanyloxy)-ethyl]-7-(tert-butyldiphenylsilanyloxy)-1-(4-methoxybenzyloxy)-2-methylheptan-3-ol 

Relevant academic research and scientific papers

A total synthesis of the antitumour macrolide rhizoxin D

An enantioselective synthesis of rhizoxin D (2), isolated from the plant pathogenic fungus Rhizopus chinensis, is described. The overall strategy is based on elaboration of the δ-lactone-substituted vinyl stannane 7 and the phosphonate-substituted vinyl i

A concise enantioselective total synthesis of rhizoxin D

A new and convergent synthesis of the antitumour macrolide rhizoxin D 2 is described. The synthesis features a Wadsworth-Emmons olefination and a facile intramolecular Stille reaction to elaborate the 16-membered macrocyclic core 5 from the vinyl iodide 3