42346-17-8Relevant academic research and scientific papers
(p-tolyl)dichlorophosphine and di(p-tolyl)chlorophosphine sources of new organophosphorus(III) and (V) compounds
Fǎgǎdar-Cosma, Eugenia,Fǎgǎdar-Cosma, Gheorghe
, p. 211 - 217 (2007/10/03)
The purpose of our present work was to study some chemical properties of p-tolyldichlorophosphine and di(p-tolyl)chlorophosphine involved in reactions with organo-lithium compounds, with 1,2-diols and also when are reactants in variants of Reformatsky and Mannich reactions, in order to obtain some new substances of trivalent and pentavalent phosphorus useful for our further investigations. All the new phosphorus(III) and (V) compounds were obtained in fair yields, and were characterized by elemental analysis, IR, and NMR spectroscopy. They will find potential synthetic utility as convenient ligands for transition metals and reagents for the preparation of phosphonium salts, for obtaining chiral substances and as biologically active ring substances.
