4235-46-5Relevant academic research and scientific papers
Singlet Fission in a Flexible Bichromophore with Structural and Dynamic Control
Aster, Alexander,Zinna, Francesco,Rumble, Christopher,Lacour, Jér?me,Vauthey, Eric
, p. 2361 - 2371 (2021)
Singlet fission (SF), i.e., the splitting of a high-energy exciton into two lower-energy triplet excitons, has the potential to increase the efficiency for harvesting spectrally broad light. The path from the photopopulated singlet state to free triplets is complicated by competing processes that decrease the overall SF efficiency. A detailed understanding of the whole cascade and the nature of the photoexcited singlet state is still a major challenge. Here, we introduce a pentacene dimer with a flexible crown ether spacer enabling a control of the interchromophore coupling upon solvent-induced self-aggregation as well as cation binding. The systematic change of solvent polarity and viscosity and excitation wavelength, as well as the available conformational phase space, allows us to draw a coherent picture of the whole SF cascade from the femtosecond to microsecond time scales. High coupling leads to ultrafast SF (2 ps), independent of the solvent polarity, and to highly coupled correlated triplet pairs. The absence of a polarity effect indicates that the solvent coordinate does not play a significant role and that SF is driven by intramolecular modes. Low coupling results in much slower SF (μ500 ps), which depends on viscosity, and leads to weakly coupled correlated triplet pairs. These two triplet pairs could be spectrally distinguished and their contribution to the overall SF efficiency, i.e., to the population of free triplets, could be determined. Our results reveal how the overall SF efficiency can be increased by conformational restrictions and control of the structural fluctuation dynamics.
High-Yield Excited Triplet States in Pentacene Self-Assembled Monolayers on Gold Nanoparticles through Singlet Exciton Fission
Kato, Daiki,Sakai, Hayato,Tkachenko, Nikolai V.,Hasobe, Taku
, p. 5230 - 5234 (2016)
One of the major drawbacks of organic-dye-modified self-assembled monolayers on metal nanoparticles when employed for efficient use of light energy is the fact that singlet excited states on dye molecules can be easily deactivated by means of energy trans
Synthesis of solution-soluble pentacene-containing conjugated copolymers
Okamoto, Toshihiro,Bao, Zhenan
, p. 10308 - 10309 (2007)
We have synthesized new-type of pentacene copolymers containing linear- and branched-dialkoxylphenyldiethynylene units via a modified Sonogashira coupling reaction at room temperature to prepare low-band gap polymers (1.7 eV). The structures of polymers
Thermally stable organic thin film transistors based on 2-(anthracen-2-yl)tetracene
He, Chao,He, Yang,He, Yaowu,Meng, Hong,Wu, Yuting,Yu, Huinan
, (2020)
Organic semiconductors with high mobility and high thermal stability are of great importance for practical application of organic electronics. To explore new semiconductors by taking advantage of the intrinsic properties of tetracene molecule, herein, we report the design and synthesis of a novel p-type tetracene derivatives, 2-(anthracen-2-yl)tetracene (TetAnt). Top contact organic thin-film transistors (OTFTs) based on TetAnt show a hole mobility of up to 0.79 cm2 V?1 s?1. In addition, a high mobility of ~0.4 cm2 V?1 s?1 is maintained even after thermal stressed to a high temperature of 290 °C, indicating the excellent thermal stability of TetAnt.
Anthrathiadiazole Derivatives: Synthesis, Physical Properties and Two-photon Absorption
Fan, Mingxuan,Chen, Guangsheng,Xiang, Yu,Li, Junbo,Yu, Xianglin,Zhang, Wenying,Long, Xueting,Xu, Liang,Wu, Jinjun,Xu, Ze,Zhang, Qichun
, p. 10898 - 10902 (2021/06/28)
Anthrathiadiazole is a key synthon for the construction of large azaacenes, however, the attachment of different substituents onto the skeleton of anthrathiadiazole is difficult but highly desirable because it could be easy to enrich the structures of aza
A Free-Radical Prompted Barrierless Gas-Phase Synthesis of Pentacene
Ahmed, Musahid,Azyazov, Valeriy N.,Bashkirov, Eugene K.,Bettinger, Holger F.,Evseev, Mikhail M.,Kaiser, Ralf I.,Lu, Wenchao,Mebel, Alexander M.,Reicherter, Florian,T?nshoff, Christina,Zhao, Long
supporting information, p. 11334 - 11338 (2020/05/16)
A representative, low-temperature gas-phase reaction mechanism synthesizing polyacenes via ring annulation exemplified by the formation of pentacene (C22H14) along with its benzo[a]tetracene isomer (C22H14) is unraveled by probing the elementary reaction of the 2-tetracenyl radical (C18H11.) with vinylacetylene (C4H4). The pathway to pentacene—a prototype polyacene and a fundamental molecular building block in graphenes, fullerenes, and carbon nanotubes—is facilitated by a barrierless, vinylacetylene mediated gas-phase process thus disputing conventional hypotheses that synthesis of polycyclic aromatic hydrocarbons (PAHs) solely proceeds at elevated temperatures. This low-temperature pathway can launch isomer-selective routes to aromatic structures through submerged reaction barriers, resonantly stabilized free-radical intermediates, and methodical ring annulation in deep space eventually changing our perception about the chemistry of carbon in our universe.
Water-soluble tetraazaporphins and fluorochrome for labeling
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, (2008/06/13)
Tetraazaporphins represented by the general formula (I): STR1 provide substances derived from organisms (e.g. antigens, antibodies, nucleotides, etc.) which have been labeled with a fluorochrome for labeling comprising the tetraazaporphin; reagents compri
Naphthalocyanine derivatives, production thereof, optical recording medium using the same, and production thereof
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, (2008/06/13)
A naphthalocyanine derivative of the formula: STR1 wherein M, Y, R1, k, l, m, n are as defined in the specification, is an effective substance for forming a recording layer on a substrate of an optical recording medium having high sensitivity w
Water-soluble tetraazaporphins and fluorochrome for labeling
-
, (2008/06/13)
Water-soluble tetraazaporphins with novel structure is suitable as a fluorochrome for labeling and provides a reagent usable for fluorescence analysis process.
Naphthalocyanine derivatives and their use in optical recording medium
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, (2008/06/13)
Novel naphthalocyanine derivatives are disclosed in the specification are useful for forming a recording layer in an optical recording medium. These derivatives are represented by the following formula (I): STR1 in which k, l, m and n, which may be the sa
