42367-12-4

Basic information

• Product Name: cis-4-phenyl-1-bromocyclohexane
• Synonyms: cis-4-phenyl-1-bromocyclohexane
• CAS NO: 42367-12-4
• Molecular Weight: 239.155
• Mol File: 42367-12-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis-4-phenyl-1-bromocyclohexane(CAS DataBase Reference)
• NIST Chemistry Reference: cis-4-phenyl-1-bromocyclohexane(42367-12-4)
• EPA Substance Registry System: cis-4-phenyl-1-bromocyclohexane(42367-12-4)

Safety Data

• Hazardous Substances Data: 42367-12-4(Hazardous Substances Data)

Upstream product

• 4894-75-1 1-phenyl-4-cyclohexanone 
• 5437-46-7 trans-4-phenylcyclohexanol 

Downstream Products

• 4994-16-5 4-phenylcyclohexene 

Relevant articles and documents

Enantioselective preparation of 4-substituted cyclohexenes by radical fragmentation of sulfoxides

(equation presented) Radical fragmentation of o-bromophenyl sulfoxides is reported. Starting from enantiomerically pure material, 4-substituted cyclohexene derivatives have been prepared with enantiomeric excesses between 70% and 86%. The key step of the process is a diastereoselective abstraction of a hydrogen atom by the initial aryl radical. The highest enantiomeric exesses have been obtained in the presence of aluminum Lewis acids.