4237-19-8

Basic information

• Product Name: 3-O-benzoyl-5-deoxy-1,2-O-isopropylidene-α-D-xylofuranose
• Synonyms: 3-O-benzoyl-5-deoxy-1,2-O-isopropylidene-α-D-xylofuranose
• CAS NO: 4237-19-8
• Molecular Weight: 278.305
• Mol File: 4237-19-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-O-benzoyl-5-deoxy-1,2-O-isopropylidene-α-D-xylofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 3-O-benzoyl-5-deoxy-1,2-O-isopropylidene-α-D-xylofuranose(4237-19-8)
• EPA Substance Registry System: 3-O-benzoyl-5-deoxy-1,2-O-isopropylidene-α-D-xylofuranose(4237-19-8)

Safety Data

• Hazardous Substances Data: 4237-19-8(Hazardous Substances Data)

Upstream product

• 6893-65-8 1,2-di-O-isopropylidene-5-O-tosyl-D-xylofuranose 
• 20031-21-4 1,2-O-isopropylidene-α-D-xylose 
• 532-20-7 D-xylofuranose 
• 98-88-4 benzoyl chloride 
• 4152-79-8 1,2-O-isopropylidene-5-methyl-5-deoxy-α-D-xylofuranose 

Downstream Products

• 4152-80-1 5-deoxy-3-O-benzoyl-1,2-di(O-acetyl)-β-D-xylofuranose 
• 4152-81-2 5-deoxy-3-O-benzoyl-1,2-di(O-acetyl)-α-D-xylofuranose 
• 1028945-18-7 C₁₉H₂₄O₈ 
• 56570-83-3 Benzoic acid (2R,3R,4R)-4-hydroxy-5-methoxy-2-methyl-tetrahydro-furan-3-yl ester 

Relevant articles and documents

First total synthesis of a naturally occurring iodinated 5′-deoxyxylofuranosyl marine nucleoside

4-Amino-7-(5′-deoxy-β-D-xylofuranosyl)-5-iodo-pyrrolo[2,3-d] pyrimidine 1, an unusual naturally occurring marine nucleoside isolated from an ascidan, Diplosoma sp., was synthesized from D-xylose in seven steps with 28% overall yield on 10 g scale. The key step was Vorbrueggen glycosylation of 5-iodo-pyrrolo[2,3-d]pyrimidine with 5-deoxy-1, 2-O-diacetyl-3-O-benzoyl-D- xylofuranose. Its absolute configuration was confirmed.