423768-14-3Relevant academic research and scientific papers
Highly enantioselective aza-Baylis-Hillman reactions catalyzed by chiral thiourea derivatives
Raheem, Izzat T.,Jacobsen, Eric N.
, p. 1701 - 1708 (2007/10/03)
We report the discovery of asymmetric aza-Baylis-Hillman (ABH) reactions of N-p-nitrobenzenesulfonylimines with methyl acrylate catalyzed by chiral thiourea derivatives. A series of aromatic imines was found to undergo coupling with methyl acrylate with u
Titanium isopropoxide as efficient catalyst for the aza-Baylis-Hillman reaction. Selective formation of α-methylene-β-amino acid derivatives
Balan, Daniela,Adolfsson, Hans
, p. 2329 - 2334 (2007/10/03)
The direct formation of α-methylene-β-amino acid derivatives is achieved using the aza version of the Baylis-Hillman protocol. The products are readily formed in a three-component one-pot reaction between arylaldehydes, sulfonamides, and α,β-unsaturated c
