42397-25-1Relevant articles and documents
Novel catalysis in the internal nanocavity of polyamine dendrimer for intramolecular michael reaction
Maeno, Zen,Mitsudome, Takato,Mizugaki, Tomoo,Jitsukawa, Koichiro,Kaneda, Kiyotomi
supporting information; experimental part, p. 801 - 803 (2012/09/22)
Poly(propyleneimine) (PPI) dendrimers functionalized with C16 alkyl chains acted as efficient tertiary amine catalysts for an intramolecular Michael reaction. The substrate was accommodated in a reactive conformation within a sterically confined nanocavity consisting of regularly arranged tertiary amino groups of the PPI dendrimers.