42437-33-2Relevant academic research and scientific papers
OXIDATIVE-REDUCTIVE TRANSMETALLATION REACTIONS OF GERMYLMERCURY COMPOUNDS WITH BIS(ETHYLBENZENE)VANADIUM AND VANADOCENE
Bochkarev, M. N.,Pankratov, L. V.,Cherkasov, V. K.,Razuvaev, G. A.,Latyaeva, V. N.,Lineva, A. N.
, p. 21 - 28 (2007/10/02)
The ionic complexHg>-+ has been obtained in the reaction of 2Hg with bis(ethylbenzene)vanadium.Dicyclopentadienylvanadium displaces mercury in 2Hg to give the covalent product Cp2VGe(C
REACTIVITY OF THALLIUM TRIS MERCURATE
Razuvaev, G. A.,Bochkarev, M. N.,Pankratov, L. V.
, p. 135 - 144 (2007/10/02)
Metallic lithium and dibenzenechromium displace thallium from (R3fGe)3HgTl*1.5DME (Rf = C6F5, DME = 1,2-dimethoxyethane) to give (R3fGe)3HgLi*3DME and fGe)4Hg>2, respectively.Reactions of thallium germylmercurate with halides of metals and organometallics in DME/EtOH solution produce ionic compounds of fGe)3Hg>-M+ type, which (depending on M ) (a) may be isolated as pure compounds, (b) disproportionate, (c) form covalent derivatives R3fGe-m or (d) undergo alcoholysis.A general scheme for the reactions has been proposed.
