1259-89-8

Basic information

• Product Name: Germane, chlorotris(pentafluorophenyl)-
• CAS NO: 1259-89-8
• Molecular Formula: C18ClF15Ge
• Molecular Weight: 609.217
• Mol File: 1259-89-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Germane, chlorotris(pentafluorophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Germane, chlorotris(pentafluorophenyl)-(1259-89-8)
• EPA Substance Registry System: Germane, chlorotris(pentafluorophenyl)-(1259-89-8)

Safety Data

• Hazardous Substances Data: 1259-89-8(Hazardous Substances Data)

Upstream product

• 42437-33-2 hexakis(pentafluorophenyl)digermane 
• 107-27-7 ethylmercury(II) chloride 
• 10038-98-9 germaniumtetrachloride 
• 1076-44-4 pentafluorophenyl lithium 
• 344-04-7 bromopentafluorobenzene 
• 59871-30-6 1,1,1-Triethyl-2,2,2-tris-pentafluorophenyl-digermane 
• 59871-31-7 1,1,1,3,3,3-Hexaethyl-2,2-bis(pentafluorphenyl)trigerman 
• 69162-04-5 (C₆F₅)3GeBi(C₂H₅)2 
• 42371-50-6 tris(pentafuorophenyl)germane 
• 54008-40-1 bis-(pentafluoro phenyl) germane 
• 10360-39-1 tris(pentafluorophenyl)germanium bromide 
• 57523-20-3 1,1,1-tris(pentafluorophenyl)-2,2,2-trichlorodigermane 
• 35406-49-6 bis[tris(pentafluorophenyl)germyl]mercury 
• 7647-01-0 hydrogenchloride 

Downstream Products

• 1064-10-4 hexaphenylditin 
• 10251-44-2 butyl tris-(pentafluoro phenyl) germane 
• 10177-70-5 hexakis-(pentafluoro phenyl) digermoxane 
• 363-72-4 Pentafluorobenzene 
• 1452-12-6 tetra(pentafluorophenyl)germanium 
• 78240-47-8 (C₆F₅)3GeP(C₆H₅)Ge(C₆F₅)3 
• 42371-50-6 tris(pentafuorophenyl)germane 

Relevant articles and documents

donor-acceptor oligogermanes: Synthesis, structure, and electronic properties

A series of oligogermanes, (Me3Si)3GeGeCl 3, (C6F5)3GeGePh3, (C6F5)3GeGe(p-Tol)3, and (C 6F5)2Ge[Ge(p-Tol)3]2, containing substituents with different electronic properties at neighboring germanium atoms were synthesized. According to X-ray diffraction studies, UV/visible spectroscopy, and quantum chemical calculations, these donor-acceptor oligogermanes are characterized by energies of electronic transitions lower than those for other similar compounds.

REACTIVITY OF THALLIUM TRIS MERCURATE

Metallic lithium and dibenzenechromium displace thallium from (R3fGe)3HgTl*1.5DME (Rf = C6F5, DME = 1,2-dimethoxyethane) to give (R3fGe)3HgLi*3DME and fGe)4Hg>2, respectively.Reactions of thallium germylmercurate with halides of metals and organometallics in DME/EtOH solution produce ionic compounds of fGe)3Hg>-M+ type, which (depending on M ) (a) may be isolated as pure compounds, (b) disproportionate, (c) form covalent derivatives R3fGe-m or (d) undergo alcoholysis.A general scheme for the reactions has been proposed.