42456-81-5Relevant academic research and scientific papers
Use of the Broensted Relationship To Detect a Mechanistic Shift for Reaction of 2-(Methylthio)ethyl Chloride with Thiophenoxide Anions
Harris, J. Milton,Sedaghat-Herati, M. R.,McManus, Samuel P.
, p. 3893 - 3894 (2007/10/02)
The linear Broensted plot for reaction of thiophenoxide ions with 2-(methylthio)ethyl chloride in DMSO changes slope for highly deactivated thiophenoxides, thus suggesting a mechanism change.Attack of a neutral nucleophile on an anionic electrophile may b
