42491-33-8

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 25979-07-1 tert-butyldichlorophosphine 
• 2501-94-2 tert-butylphosphine 

Downstream Products

• 75-77-4 chloro-trimethyl-silane 
• 80705-56-2 tert-Butyl<(trimethylsiloxy)methylen>phosphan 
• 73424-12-1 tert-butyl<2,2-diphenyl-1-(trimethylsiloxy)ethylidene>phosphine 
• 75388-01-1 1,2-Bis(1,1-dimethylethyl)-3,4-bis(trimethylsilyloxy)-1,2-diphospheten 
• 97053-96-8 1-tert-Butyl-2--1-(trimethylsilyl)diphosphan 
• 80269-49-4 tert-butyl<2-(methoxycarbonyl)-2-phenyl-1-(trimethylsiloxy)ethylidene>phosphine 
• 91749-15-4 tert-butyl<(α-methoxybenzyl)(trimethylsilyl)carbamoyl>(trimethylsilyl)phosphine 
• 112100-40-0 C₇H₁₈Cl₂P₂Si 
• 4099-46-1 bis(trimethylsilyl)selenide 
• 122631-90-7 t-butyl-perselenophosphonic anhydride 
• 4551-16-0 bis(trimethylsilyl) telluride 
• 87869-43-0 2,3,4-Tri-tert-butyl-[1,2,3,4]telluratriphosphetane 
• 93545-11-0 1,2-Di-tert-butyl-3,4-bis(2-phenylethenyl)-3,4-bis(trimethylsilyloxy)-1,2-diphosphetan 
• 80269-54-1 tert-butyl<2,2-diphenyl-1-(trimethylsiloxy)vinyl>(trimethylsilyl)phosphine 

Relevant academic research and scientific papers

Phosphacycloalkyldiones: synthesis and coordinative behaviour of 6- And 7-member cyclic diketophosphanyls

Glutaryl and adipoyl chlorides undergo facile condensation with the bis(silyl)phosphanes RP(SiMe3)2(R = Me,nBu,tBu, Ph, Mes) to afford exclusively the phosphacycloalkyldiones (CH2)n(C)2PR (n= 3,4). Characterised spectroscopically and, for R = Ph, Mes (n= 3) crystallographically, the macrocycles are conformationally fluxional in solution and appreciably moisture sensitive. Though seemingly resistant to chemical oxidation at phosphorus, coordination is readily achieved, as illustrated by isolation oftrans-[Pt(PEt3){P(Ph)(CO)2(CH2)3}Cl2] and a series of tungsten pentacarbonyl complexes, which are characterised crystallographically and by infrared and NMR spectroscopy. Together, these data suggest the macrocycles to be relatively weak σ-donors with no appreciable π-acceptor character.

Organometalphosphine-Substituted Transition Metal Complexes, XXVI Dicarbonyl Nitrosyl Organometal Phosphine Cobalt Complexes

The reactions of tricarbonyl nitrosyl cobalt with tri-tert-butylphosphine, di(tert-butyl)-trimethylsilyl-, germyl-, stannylphosphine, tert-butyl-bis(trimethylsilyl)-, -(germyl)-, -(stannyl)phosphine, as well as with tris(trimethylsilyl)-, -(germyl)-, and -(stannyl)phosphine result in the elimination of one CO-ligand and the formation of corresponding dicarbonyl-nitrosyl-organometal phosphine cobalt complexes.The NMR spectra of the products are reported and discussed. - Keywords: Organometal Phosphines, Dicarbonyl-nitrosyl Cobalt Complexes, NMR Spectra