42497-87-0

Basic information

• Product Name: Benzene, 1-nitro-4-[[(4-nitrophenyl)thio]methyl]-
• CAS NO: 42497-87-0
• Molecular Formula: C13H10N2O4S
• Molecular Weight: 290.299
• Mol File: 42497-87-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1-nitro-4-[[(4-nitrophenyl)thio]methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-nitro-4-[[(4-nitrophenyl)thio]methyl]-(42497-87-0)
• EPA Substance Registry System: Benzene, 1-nitro-4-[[(4-nitrophenyl)thio]methyl]-(42497-87-0)

Safety Data

• Hazardous Substances Data: 42497-87-0(Hazardous Substances Data)

Upstream product

• 100-11-8 1-bromomethyl-4-nitro-benzene 
• 99-99-0 1-methyl-4-nitrobenzene 
• 100-32-3 di(p-nitrophenyl) disulfide 

Downstream Products

• 42497-92-7 1-nitro-4-(4-nitrophenylsulfonylmethyl)benzene 
• 17530-86-8 (4-nitro-benzyl)-(4-nitro-phenyl)-sulfoxide 
• 42497-98-3 4-(4-amino-benzylsulfanyl)-aniline 
• 4389-37-1 4-sulfanilylmethyl-aniline 

Relevant articles and documents

Sulfite-promoted one-pot synthesis of sulfides by reaction of aryl disulfides with alkyl halides

A sodium dithionite, sodium thiosulfate and rongalite promoted one-pot synthesis of aryl alkyl sulfides at room temperature has been developed. The reactions of a range of disulfides with alkyl halides proceeded smoothly in the presence of rongalite. Possible reaction pathways are discussed and the effects of these sulfites on disulfides are investigated. The important features of this protocol are metal-free, strong-base-free, and mild reaction conditions, operational simplicity, short reaction times and high yields of products. Georg Thieme Verlag Stuttgart.