425-24-1Relevant academic research and scientific papers
The Decomposition of t-Butyl Heptafluoroperoxybutyrate in Aromatic and Aliphatic Solvents
Sawada, Hideo,Hagii, Hidehiko,Aoshima, Kazuyoshi,Yoshida, Masato,Kobayashi, Michio
, p. 3448 - 3452 (2007/10/02)
Kinetical studies and products analyses of the thermal decomposition of t-butyl heptafluoroperoxybutyrate (TBH) in benzene, octane, nitrobenzene, pyridine, and methoxybenzene have been carried out.In benzene and octane, the decoposition appears to be entirely a radical process.In nitrobenzene and pyridine, the reactions are found to give ionic decomposition proudcts exclusively.On the other hand, the decomposition of TBH in methoxybenzene is characteristic of mixed ionic and radical cleavages.
Thermal Decomposition of t-Butyl Heptafluoroperoxybutyrate
Sawada, Hideo,Hagii, Hidehiko,Aoshima, Kazuyoshi,Arai, Takeshi
, p. 1161 - 1162 (2007/10/02)
The decomposition of t-butyl heptafluoroperoxybutyrate (TBH) was studied in both toluene and methanol.Kinetic and product studies from the thermolysis showed that this peroxy ester decomposes heterolytically in nonpolar solvents like toluene with homolysis, whereas in methanol this peroxy ester undergoes principally transesterification.
