4251-20-1Relevant academic research and scientific papers
Synthesis and UV photolysis of oligodeoxynucleotides that contain 5-(phenylthiomethyl)-2'-deoxyuridine: a specific photolabile precursor of 5-(2'-deoxyuridilyl)methyl radical.
Romieu,Bellon,Gasparutto,Cadet
, p. 1085 - 1088 (2007/10/03)
[formula: see text] The title exocyclic radical (2) is generated via photochemical cleavage of 5-(phenylthiomethyl)-2'-deoxyuridine (8). The latter thionucleoside (8) was successfully incorporated into DNA oligomers by automated DNA synthesis using phosphoramidite chemistry. UV exposure of 8 containing oligonucleotides under (an)aerobic conditions gives rise to specific base lesions. The photoproducts have been isolated and further characterized on the basis of detailed NMR and mass spectrometric analyses.
SYNTHESE SIMPLIFIEE DE SONDES MIXTES AVEC DES TRIAZOLO-NUCLEOSIDES
Huynh-Dinh, T.,d'Estaintot, B. Langlois,Allard, P.,Igolen, J.
, p. 431 - 434 (2007/10/02)
The incorporation of triazolo-nulleosides during the synthesis of a specific sequence yields, after treatment with a mixture of pyridine aldoximate- tetramethyl guanidine- concentrated ammonia, mixed probes oligonucleotides with practically equimolecular amounts of T/MeC and G/NH2A at the degenerate sites.
