42548-90-3

Upstream product

• 7437-61-8 2-methyl-3,4-epoxy-1-butene 
• 591-50-4 iodobenzene 
• 100-56-1 phenylmercury(II) chloride 
• 75321-72-1 ethyl (E,Z)-3-methyl-4-phenylbut-2-enoate 
• 103-79-7 1-phenyl-acetone 

Downstream Products

• 503003-88-1 2-methyl-1-phenyl-but-3-ene-2-thiol 
• 503003-68-7 C₁₁H₁₃NOS 
• 503003-83-6 dithiocarbonic acid S-(1-benzyl-1-methyl-allyl) ester S-methyl ester 
• 34126-21-1 (R)-3-methyl-4-phenylbutan-1-ol 
• 71279-67-9 3-Cyclopentylmethoxy-2,2-dimethyl-cyclopropanecarboxylic acid (E)-3-methyl-4-phenyl-but-2-enyl ester 

Relevant academic research and scientific papers

Synthesis of Allylic Alcohols via Palladium-Catalyzed Cross-Coupling of Vinylic Epoxides and Aryl or Vinylic Halides and Triflates

Palladium acetate in the presence of sodium formate, n-Bu4NCl, and diisopropylethylamine catalyzes the cross-coupling of vinylic epoxides with aryl or vinylic halides and triflates to form allylic alcohols in good yield.

Development of general methods for the synthesis of new substituted allyl bromides as promising alkenylating agents

A general procedure has been developed for the synthesis of hitherto unknown substituted allyl bromides. The procedure includes preparation of the corresponding α,β-unsaturated carboxylic acid esters from accessible ketones according to the Horner-Emmons

Synthesis and biological activity of permethrinic acid analogs containing various substituents in position 2 of the cyclopropane ring

A number of permethrinic acid ethyl ester derivatives having various substituents [Et, Pr, Ph, Ph(CH2) n (n = 1, 2), etc.] in position 2 of the cyclopropane ring were synthesized, and their insecticidal acivity against typhoid flies, rice weevils, and bean aphides, as well as juvenoid activity on flour beetle chrysalises, was studied. The newly synthesized compounds turned out to exhibit weak insecticidal activity against standard insects but pronounced juvenile hormone activity, which differentiates them from permethrinic acid esters.

Thioepoxide formation by ring closure of allylthiyl radicals - A novel rearrangement of allylic thionitrites

Tertiary allylic thionitrites undergo thermal rearrangement to α,β-episulfide nitroso dimers via ring closure of allylthiyl radicals.

SYNTHESIS OF ALLYLIC ALCOHOLS VIA ORGANOPALLADIUM ADDITIONS TO UNSATURATED EPOXIDES

The reaction of aryl- and vinylpalladium compounds with vinylic and allylic epoxides provides an excellent, high yielding, regio- and stereoselective route to functionally substituted allylic alcohols which can be made catalytic in palladium.