425613-27-0

Basic information

• Product Name: (SnH((CH₃)3C₆H₂)2)2
• Synonyms: (SnH((CH₃)3C₆H₂)2)2
• CAS NO: 425613-27-0
• Molecular Weight: 716.181
• Mol File: 425613-27-0.mol

Chemical Properties

• CAS DataBase Reference: (SnH((CH₃)3C₆H₂)2)2(CAS DataBase Reference)
• NIST Chemistry Reference: (SnH((CH₃)3C₆H₂)2)2(425613-27-0)
• EPA Substance Registry System: (SnH((CH₃)3C₆H₂)2)2(425613-27-0)

Safety Data

• Hazardous Substances Data: 425613-27-0(Hazardous Substances Data)

Upstream product

• 425613-21-4 bis(2,4,6-trimethylphenyl)stannane 
• 1333-74-0 hydrogen 

Downstream Products

• 425613-21-4 bis(2,4,6-trimethylphenyl)stannane 
• 425613-41-8 (Sn((CH₃)3C₆H₂)2)2H⁽²⁾H 

Relevant articles and documents

A new mechanism for metal-catalyzed stannane dehydrocoupling based on α-H-elimination in a hafnium hydrostannyl complex

The hafnium hydrostannyl complex CpCp*Hf(SnHMes2)Cl (Cp* = η5-C5Me5) has been synthesized from the reaction of CpCp*Hf(H)Cl with Mes2SnH2. This compound has been identified as an intermediate in the metal-catalyzed dehydrocoupling of Mes2SnH2 to the distannane Mes2HSnSnHMes2 (Mes = 2,4,6-trimethylphenyl). The dehydrocoupling in this system appears to occur by elimination of :SnMes2 from CpCp*Hf(SnHMes2)Cl, with Sn-Sn bond formation proceeding via insertion of the stannylene into a Sn-H bond. Copyright