4259-43-2

Usage

Uses

Used in Refrigeration Industry:
1,1,1-Trichloropentafluoropropane is used as a refrigerant for its ability to absorb and release heat efficiently, which is crucial in cooling systems. Its high vapor pressure and low boiling point facilitate the refrigeration cycle.
Used in Foam Blowing Industry:
In the foam blowing industry, 1,1,1-Trichloropentafluoropropane serves as a foam blowing agent, helping to create lightweight and insulating materials. Its properties allow for the expansion of foams during the manufacturing process.
Despite these applications, the use of 1,1,1-Trichloropentafluoropropane is under scrutiny and restriction due to its environmental impact. Efforts are being made to find and adopt alternative substances that are more environmentally friendly and have less harmful effects on the ozone layer and global climate.

InChI:InChI=1/C3Cl3F5/c4-2(5,6)1(7,8)3(9,10)11

Upstream product

• 116-14-3 polytetrafluoroethylene 
• 75-71-8 Dichlorodifluoromethane 
• 75-69-4 trichlorofluoromethane 
• 422-02-6 3-chloro-1,1,1,2,2-pentafluoropropane 

Downstream Products

• 422-02-6 3-chloro-1,1,1,2,2-pentafluoropropane 
• 1599-41-3 2,2,3-trichloro-1,1,1,3,3-pentafluoropropane 
• 754-12-1 2,3,3,3-tetrafluoro-propene 
• 422-56-0 3,3-dichloro-1,1,1,2,2-pentafluoropropane 
• 422-86-6 perfluoropropyl chloride 
• 421-48-7 1,1,1,2-tetrafluoropropane 
• 677-55-4 1-chloro-1,1,2,2,3-pentafluoropropane 
• 162763-52-2 3,4-dichlorodecafluorohex-3-ene 
• 1814-88-6 1,1,1,2,2-pentafluoropropane 
• 421-07-8 1,1,1-trifluoropropane 
• 18599-03-6 1.1.1.2.2-Pentafluor-3.3-dichlor-5-methyl-hexen-(5) 

Relevant academic research and scientific papers

PROCESSES FOR THE SYNTHESIS OF 3-CHLOROPERFLUORO-2-PENTENE, OCTAFLUORO-2-PENTYNE, AND 1,1,1,4,4,5,5,5-OCTAFLUORO-2-PENTENE

Disclosed is a process comprising reacting CF3CF2CCI2CF2CF3 (CFC-41 -10mca) with hydrogen in the presence of a dehalogenation catalyst to produce CF3CF2CCI=CFCF3 (CFC-1419myx). Also disclosed herein is a process comprising reacting CF3CF2CCI=CFCF3 (CFC- 1419myx) with hydrogen in the presence of a dehalogenation catalyst to produce CF3CF2C≡CCF3 (octafluoro-2-pentyne). Also disclosed herein is a process comprising reacting CF3CF2CCI2CF2CF3 (CFC-41 -10mca) with hydrogen in the presence of a dehalogenation catalyst to produce CF3CF2C≡CCF3 (octafluoro-2-pentyne). In addition, a process for reacting CF3CF2C≡CCF3, in a pressure vessel, with a Lindlar catalyst and hydrogen to produce CF3CF2CH=CHCF3 (1,1,1,4,4,5,5,5-octafluoro-2- pentene) is disclosed.

PROCESSES FOR PRODUCING AND COMPOSITIONS COMPRISING 2,3,3,3-TETRAFLUOROPROPENE AND/OR 1,2,3,3-TETRAFLUOROPROPENE

A process is disclosed for making CF3CF=CH2 or mixtures thereof with CHF=CFCHF2. The process involves contacting CCI3CF2CF3 and optionally CCI2FCF2CCIF2 with H2 in the presence of a catalyst including a catalytically effective amount of palladium supported on a support of alumina, fluorided aluminaand/or aluminum fluoride, to produce a product mixture including CH2=CFCF3 (and when CCI2FCF2CCIF2 is present, CHF=CFCHF2); recovering CH2=CFCF3 or a mixture thereof with CHF=CFCHF2 from the product mixture; and optionally, separating at least a portion of any CHF=CFCHF2 in the product mixture from the CH2=CFCF3 in the product mixture. The mole ratio of H2 to the total of CCI3CF2CF3 and CCI2FCF2CCIF2 fed to the reaction zone is between about 1 :1 and about 5:1. The present invention also provides another process for making CH2=CFCF3 Or mixtures thereof with CHF=CFCHF2 This process involves (a) reacting CCI3CF2CF3 and optionally CCI2FCF2CCIF2 with H2 in the presence of a catalytically effective amount of a hydrogenation catalyst to form CH3CF2CF3 (and when CCI2FCF2CCIF2 is present, CH2FCF2CHF2); (b) dehydrofluorinating CH3CF2CF3 and optionally any CH2FCF2CHF2 from (a) to form a product mixture including CH2=CFCF3, and if CH2FCF2CHF2 is present, CHF=CFCHF2; (c) recovering CH2=CFCF3 or a mixture thereof with CHF=CFCHF2 from the product mixture formed in (b); and optionally (d) separating at least a portion of any CHF=CFCHF2 in the product mixture formed in (b) from the CH2=CFCF3 in the product mixture formed in (b). The present invention also provides compositions involving CH2=CFCF3 and/or CHF=CFCHF2, including compositions useful as refrigerants, foam blowing agents, cleaning agents and aerosols and azeotropic compositions involving (a) CF2HCF=CFH and (b) HF.

19F nuclear magnetic resonance studies of halogenated propanes

The relationship between 19F chemical shifts in halogenated propanes and their structures are elucidated using MNDO calculations to determine the population of rotamers.The pairs of atom gauche to a fluorine atom and van der Waals interaction between the two terminal substituents are responsible for the 19F chemical shifts.The differences among chemical shifts in diastereomers are also discussed in terms of the conformation of molecule.