426822-95-9Relevant academic research and scientific papers
Stereochemistry of cuprate-mediated conjugate additions of a 17-iodoandrost-16-ene to E- and Z-6-methylhept-2-en-4-one
Andersen, Denise L.,Back, Thomas G.
, p. 1797 - 1808 (2001)
(3S,15R)-15-(Benzyloxy)-3-[(tert-butyldimethylsilyl)oxy]-17-iodoandrosta -5, 16-diene (3) was prepared from the corresponding 17-hydrazone 9 with iodine in the presence of tetramethylguanidine. The vinyl iodide 3 was converted into the corresponding organ
