42738-69-2Relevant academic research and scientific papers
Biomimetic-Inspired Syntheses of Myrtucommuacetalone and Myrtucommulone J
Liu, Hongxin,Huo, Luqiong,Yang, Bao,Yuan, Yunfei,Zhang, Weimin,Xu, Zhifang,Qiu, Shengxiang,Tan, Haibo
, p. 4786 - 4789 (2017)
Driven by bioinspiration and appreciation of their structures, the first biomimetic total syntheses with structural revision of the acylphloroglucinols myrtucommulone J and myrtucommuacetalone, two biologically meaningful natural products, were achieved through a biosynthetic hemiacetalization/dehydration/[3 + 3]-type cycloaddition domino sequence with high step efficiency. These syntheses result in a corrected structure for myrtucommulone J.
