42797-62-6Relevant academic research and scientific papers
Investigations on the Conformation of 2-Diazo-1,3-diketones
Lauer, Wolfgang,Krause, Volker,Wegenroth, Horst,Meier, Herbert
, p. 465 - 470 (2007/10/02)
Conformational analyses of 2-diazo-1,3-diketones (2a-f) with bulky substituents are performed by applying 1H- and 13C-NMR measurements in solution (and in solid state).
β-Ketocarboxylic Esters with trans-Enolization
Meier, Herbert,Lauer, Wolfgang,Krause, Volker
, p. 3382 - 3393 (2007/10/02)
Open-chained β-ketocarboxylic esters 10/11, existing predominantly in the E-configuration 2 of the enol form, can be generated by the introduction of mesityl groups.The energy gain by the intramolecular hydrogen bridge in the Z-configurations 1 is compens
