42842-58-0Relevant academic research and scientific papers
Silver-Catalyzed Allylation of Ketones and Intramolecular Cyclization through Carbene Intermediates from Cyclopropenes under Ambient Conditions
Nakano, Takeo,Endo, Kohei,Ukaji, Yutaka
, p. 713 - 721 (2016/03/09)
Tandem C-C bond formation was achieved through silver-catalyzed ring-opening of cyclopropenes via carbene intermediates. The reaction of cyclopropenes in the presence of a silver catalyst gave indene derivatives under ambient conditions. In contrast, the
Synthesis of highly substituted indene derivatives by Br?nsted acid catalyzed Friedel-Crafts reaction of homoallylic alcohols
Zhang, Xiaoxiang,Teo, Wan Teng,Rao, Weidong,Ma, Dik-Lung,Leung, Chung-Hang,Chan, Philip Wai Hong
, p. 3881 - 3884 (2014/07/08)
An efficient synthetic method to prepare highly substituted indenes in moderate to excellent yields that relies on Br?nsted acid catalyzed Friedel-Crafts reaction of homoallylic alcohols under mild conditions is described.
Inter- versus Intramolecular Friedel-Crafts Reaction of Phenyl-substituted Dichlorocyclopropanes
Anke, Lutz,Weyerstahl, Peter
, p. 613 - 619 (2007/10/02)
Friedel-Crafts reactions of the phenyl-substituted dichlorocyclopropanes 1-9 show different results.Thus, 1 (-> 10, 11), 3 (-> 12), 4(-> 13), 6 (-> 14), 8 (-> 15), and 9 (-> 16) yield indenes by the known intermolecular reaction with benzene.However, 2 (-
Ozonolysis of a Series of 1-Substituted Indenes. The Substituent Steric Effects on Ozonide Exo/Endo Ratios
Miura, Masahiro,Nojima, Masatomo,Kusabayashi, Shigekazu,McCullough, Kevin J.
, p. 2932 - 2936 (2007/10/02)
The ozonolysis of a series of disubstituted (1,2 and 1,3) and trisubstituted (1,2,3) indenes 1-28 in carbon tetrachloride at 20 deg C has been investigated.The major product in each case was the corresponding bicyclic ozonide, usually obtained as a mixtur
Sigmatropic Indenyl Rearrangements Induced by Electronic Excitation
Padwa, Albert,Goldstein, Steven,Loza, Roman,Pulwer, Mitchell
, p. 1858 - 1868 (2007/10/02)
The photochemical rearrangement of several arylalkyl substituted indenes has been studied.The rearrangements were shown to be derived from the ?,?* singlet state since triplet sensitization led to no reaction or else resulted in a Paterno-Buchi
